88329-71-9Relevant academic research and scientific papers
Unprecedented 1,4-stannatropy: Effective generation of azomethine ylides as nitrile ylide equivalents from N-(stannylmethyl)thioamides
Komatsu, Mitsuo,Kasano, Yukihiro,Yonemori, Jin-Ichi,Oderaotoshi, Yoji,Minakata, Satoshi
, p. 526 - 528 (2008/02/05)
Generation and cycloaddition of less- or non-stabilized azomethine ylides, or nitrile ylide equivalents, via unprecedented 1,4-stannatropy of N-(tributylstannylmethyl)thioamides were achieved. The reactions with dipolarophiles, such as electron-deficient alkenes and alkynes, afforded corresponding pyrrolidine and pyrrole derivatives effectively. The Royal Society of Chemistry 2006.
Generation of Azomethine Ylides via the Desilylation Reaction of Immonium Salts
Padwa, Albert,Haffmanns, Gunter,Tomas, Miguel
, p. 3314 - 3322 (2007/10/02)
Generation of intermediates having azomethine ylide reactivity was achieved by the reaction of several ethanol or thioimidate derivatives with methyl iodide followed by treatment of the resulting imine with (trimethylsilyl)methyl triflate.Desilylation of
CESIUM FLUORIDE INDUCED DESILYLATION REACTION OF IMMONIUM SALTS DERIVED FROM VINYLOGOUS AMIDES
Padwa, Albert,Haffmanns, Gunter,Tomas, Miguel
, p. 4303 - 4306 (2007/10/02)
The cesium fluoride induced desilylation reaction of immonium salts derived from amides, thioamides and vinylogous amides provides access to reactive azomethine ylides in synthetically useful yields.
