88331-96-8

Upstream product

• 69557-83-1 methyl-4-O-benzoyl-α-L-rhamnopyranoside 
• 98-88-4 benzoyl chloride 
• 89202-42-6 methyl 3-O-acetyl-2,4-di-O-benzoyl-α-L-rhamnopyranoside 
• 89202-43-7 methyl 2,4-di-O-benzoyl-3-O-benzyl-α-L-rhamnopyranoside 
• 101068-97-7 Benzoic acid (2S,3S,4S,5R,6R)-4-acetoxy-5-hydroxy-6-methoxy-2-methyl-tetrahydro-pyran-3-yl ester 
• 75336-82-2 Methyl 3-O-benzyl-α-L-rhamnopyranoside 
• 1128-40-1 methyl L-rhamnopyranoside 
• 101068-96-6 Benzoic acid (2S,3S,4R,5R,6R)-4,5-diacetoxy-6-methoxy-2-methyl-tetrahydro-pyran-3-yl ester 
• 14133-63-2 methyl 2,3-O-isopropylidene-α-L-rhamnoside 
• 14917-55-6 methyl 6-deoxy-α-L-mannopyranoside 
• 707-07-3 orthobenzoic acid trimethyl ester 
• 52681-72-8 methyl-4-O-benzoyl-2,3-O-isopropylidene-α-L-rhamnopyranoside 

Downstream Products

• 142967-73-5 methyl O-(3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1->3)-2,4-di-O-benzoyl-α-L-rhamnopyranoside 
• 89202-43-7 methyl 2,4-di-O-benzoyl-3-O-benzyl-α-L-rhamnopyranoside 
• 88337-87-5 methyl 2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl-(1->3)-2,4-di-O-benzoyl-α-L-rhamnopyranoside 
• 88331-97-9 methyl 3-O-(2-O-acetyl-3,4-di-O-benzyl-α-L-rhamnopyranosyl)-2,4-di-O-benzoyl-α-L-rhamnopyranoside 
• 142967-76-8 methyl O-(2,4-di-O-benzoyl-3-O-bromoacetyl-α-L-rhamnopyranosyl)-(1->3)-2,4-di-O-benzoyl-α-L-rhamnopyranoside 
• 139760-05-7 Methyl O-(2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-(1->3)-2,4-di-O-benzoyl-α-L-rhamnopyranoside 
• 145243-67-0 2,4-di-O-benzoyl-3-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-α-L-rhamnopyranoside de methyle 
• 139760-12-6 C₆₁H₆₀O₂₃ 
• 139760-15-9 Methyl O-(2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-(1->3)-(2,4-di-O-benzoyl-α-L-rhamnopyranosyl)-(1->2)-3-O-benzoyl-4,6-O-benzylidene-α-D-galactopyranoside 
• 142967-83-7 methyl O-(2,4-di-O-benzoyl-3-O-bromoacetyl-α-L-rhamnopyranosyl)-(1-3)-O-(2,4-di-O-benzoyl-α-L-rhamnopyranosyl)-(1-2)-4,6-O-benzylidene-3-O-benzoyl-α-D-galactopyranoside 
• 139869-57-1 C₅₉H₅₇ClO₂₁ 
• 142967-80-4 methyl O-(3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1-3)-O-(2,4-di-O-benzoyl-α-L-rhamnopyranosyl)-(1-3)-2,4-di-O-benzoyl-α-L-rhamnopyranoside 
• 142967-84-8 methyl O-(2,4-di-O-benzoyl-α-L-rhamnopyranosyl)-(1-3)-O-(2,4-di-O-benzoyl-α-L-rhamnopyranosyl)-(1-2)-4,6-O-benzylidene-3-O-benzoyl-α-D-galactopyranoside 
• 142967-81-5 methyl O-(2-acetamido-2-deoxy-3,4,6-tri-O-acetyl-α-D-glucopyranosyl)-(1-3)-O-(2,4-di-O-benzoyl-α-L-rhamnopyranosyl)-(1-3)-2,4-di-O-benzoyl-α-L-rhamnopyranoside 

Relevant academic research and scientific papers

Convergent synthesis of an octasaccharide fragment of the O-specific polysaccharide of Shigella dysenteriae type 1

A stereocontrolled, convergent synthesis is described of the linear octasaccharide methyl glycoside α-L-Rhap-(1 -> 2)-α-D-Galp-(1 -> 3)-α-GlcpNAc-(1 -> 3)-α-L-Rhap-(1 -> 3)-α-L-Rhap-(1 -> 2)-α-D-Galp-(1 -> 3)-α-D-GlcpNAc-(1 -> 3)-α-L-Rhap-OMe (11), which

SYNTHESIS OF THE O-SPECIFIC POLYSACCHARIDE OF SHIGELLA FLEXNERI

A regular heteropolysaccharide built of tetrasaccharide repeating units is synthesised by means of regio- and stereospecific polycondensation of tritylated cyanoethylidene derivative.The polysaccharide obtained is identical with the O-antigenic polysaccharides of Shigella flexneri serotypes 3b, 3c, and variant Y.It also represents the basic chain of O-antigenic polysaccharides of all serotypes of this bacterium.

ARTIFICIAL CARBOHYDRATE ANTIGENS: A BLOCK SYNTHESIS OF A LINEAR, TETRASACCHARIDE REPEATING-UNIT OF THE Shigella flexneri VARIANT Y POLYSACCHARIDE

Glycosylation of methyl 2,4-di-O-benzoyl-α-L-rhamnopyranoside with 2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl bromide gave methyl 2,4-di-O-benzoyl-3-O-(2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside (4) in 93percent yield.Conversion of 4 into th