88364-54-9

Upstream product

• 201230-82-2 carbon monoxide 
• 589-15-1 1-bromomethyl-4-bromobenzene 

Downstream Products

• 1374152-32-5 C₁₅H₁₀Br₂N₂O₂ 
• 1374152-94-9 C₂₇H₁₉Br₂N₃O₂ 
• 1374152-93-8 C₂₄H₁₆Br₂N₄O₂ 
• 1374152-92-7 C₂₃H₁₆Br₂FN₃O₂ 
• 1374152-91-6 C₂₄H₁₉Br₂N₃O₃ 
• 1374152-90-5 C₂₃H₁₆Br₃N₃O₂ 
• 1374152-83-6 C₂₃H₁₇Br₂N₃O₂ 

Relevant academic research and scientific papers

CATALYTIC PHASE TRANSFER CARBONYLATION OF BENZYL HALIDES WITH IRON PENTACARBONYL.

Benzyl halides are readily carbonylated to arylacetic acids in a two-phase system (aqueous sodium hydroxide (1M), tetrabutylammonium sulfate ; organic phase (CH2Cl2 or C6H6 or C6H5CH3)), using a catalytic amount of the cheap, easy to handle iron pentacarbonyl under carbon monoxide atmosphere.

IRON PENTACARBONYL MEDIATED COUPLING OF BENZYL HALIDES TO KETONES UNDER MILD PHASE TRANSFER CONDITIONS.

In a two-phase system (saturated aqueous calcium hydroxide, tetrabutylammonium sulfate, dichloromethane, iron pentacarbonyl) benzyl bromides are readily carbonylated to dibenzyl ketones ; α-α' dibromoorthoxylene yields the o-quinodimethane iron tricarbonyl cmplex 8.It is inferred that the reactions proceed through transient generation of the tetracarbonyl ferrate dianion.