CATALYTIC PHASE TRANSFER CARBONYLATION OF BENZYL HALIDES WITH IRON PENTACARBONYL.

DOI: 10.1016/S0040-4039(00)88248-9

Source and publish data:

Tetrahedron Letters p. 4005 - 4008 (1983)

Update date:2022-08-04

Topics:

Authors:

Tanguy, Guy

Weinberger, Berndt

Abbayes, Herve des

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Article abstract of DOI:10.1016/S0040-4039(00)88248-9

Benzyl halides are readily carbonylated to arylacetic acids in a two-phase system (aqueous sodium hydroxide (1M), tetrabutylammonium sulfate ; organic phase (CH2Cl2 or C6H6 or C6H5CH3)), using a catalytic amount of the cheap, easy to handle iron pentacarbonyl under carbon monoxide atmosphere.

Full text of DOI:10.1016/S0040-4039(00)88248-9

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