88392-03-4Relevant articles and documents
Oxidative displacement and addition reactions of F-tert -butyl hypochlorite with metal chlorides and oxidative additions to several elements
Canich, Joann M.,Gard, Gary L.,Shreeve, JeaN'Ne M.
, p. 441 - 444 (2008/10/08)
Transition-metal and post-transition-metal chlorides underwent oxidative displacement and oxidative addition reactions with F-tert-butyl hypochlorite to form new F-tert-butoxides. Thus, when (CF3)3COCl was reacted with VOCl3, TiCl4, and CrO2Cl2, the stable compounds VO[(CF3)3CO]3, Ti[(CF3)3CO]4, and CrO2[(CF3)3CO]2 were formed. With Vaska's compound, oxidative addition occurred at iridium but the phenyl groups of P(C6H5)3 were also involved. UCl4, Cu2Cl2, SnCl4, and SiCl4 did not react under the experimental conditions used. F-tert-Butyl hypochlorite has also been shown to add oxidatively to such elements as sulfur, lead, tellurium, bismuth, and iodine to form S[(CF3)3CO]4, Pb[(CF3)3CO]2, Te[(CF3)3CO]4, Bi[(CF3)3CO]3, and I[(CF3)3CO]3, respectively. With (C2H5)2NH, (CF3)3COH formed a 1:1 adduct.