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ansa-METALLOCENE DERIVATIVES. V. SYNTHESIS OF TETRAMETHYLETHYLENE-BRIDGED TITANOCENE AND ZIRCONOCENE DERIVATIVES VIA REDUCTIVE FULVENE COUPLING
Schwemlein, Heinz,Brintzinger, Hans H.
, p. 69 - 74 (1983)
Titanocene and zirconocene derivatives with an interannular tetramethylethylene bridge can be made by reductive coupling of 6,6-dimethylfulvene with sodium amalgam, sodium anthracenide, or magnesium metal/CCl4 as reducing agents and subsequent reaction of
