ansa-METALLOCENE DERIVATIVES. V. SYNTHESIS OF TETRAMETHYLETHYLENE-BRIDGED TITANOCENE AND ZIRCONOCENE DERIVATIVES VIA REDUCTIVE FULVENE COUPLING

DOI: 10.1016/0022-328X(83)85118-3

Source and publish data:

Journal of Organometallic Chemistry p. 69 - 74 (1983)

Update date:2022-08-05

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Authors:

Schwemlein, Heinz

Brintzinger, Hans H.

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Article abstract of DOI:10.1016/0022-328X(83)85118-3

Titanocene and zirconocene derivatives with an interannular tetramethylethylene bridge can be made by reductive coupling of 6,6-dimethylfulvene with sodium amalgam, sodium anthracenide, or magnesium metal/CCl4 as reducing agents and subsequent reaction of

Full text of DOI:10.1016/0022-328X(83)85118-3

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