883972-65-4

Basic information

• Product Name: C₁₆H₁₄O
• Synonyms: C₁₆H₁₄O
• CAS NO: 883972-65-4
• Molecular Weight: 222.287
• Mol File: 883972-65-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: C₁₆H₁₄O(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₆H₁₄O(883972-65-4)
• EPA Substance Registry System: C₁₆H₁₄O(883972-65-4)

Safety Data

• Hazardous Substances Data: 883972-65-4(Hazardous Substances Data)

Upstream product

• 625-95-6 3-Iodotoluene 
• 4187-87-5 1-Phenyl-2-propyn-1-ol 
• 100-52-7 benzaldehyde 
• 766-82-5 1-ethynyl-3-methyl-benzene 

Downstream Products

• 1354640-63-3 1-(3-(2-bromo-4,5-dimethoxybenzyloxy)-3-phenylprop-1-ynyl)-3-methylbenzene 
• 1354640-77-9 C₂₅H₂₄O₃ 
• 57830-64-5 3′-methylcinnamanilide 
• 1374030-84-8 1-(3-methoxy-3-phenylprop-1-ynyl)-3-methylbenzene 
• 13565-44-1 (E)-3-phenyl-1-(m-tolyl)prop-2-en-1-one 
• 14674-99-8 1-phenyl-3-(3-methylphenyl)prop-2-yn-1-one 
• 16619-29-7 3-(3-methylphenyl)-1-phenyl-2-propen-1-one 

Relevant articles and documents

Flexible Construction of Functionalized-Pyrroles under Palladium or Copper Catalysis in the Presence of BF3 ? Et2O

We have developed a flexible approach enabling the access to highly functionalized pyrroles under palladium or copper catalysis in the presence of BF3 ? Et2O. This catalytic methodology utilizes commercially available amines as react

Gold(I)-catalyzed decarboxylation of propargyl carbonates: Reactivity reversal of the gold catalyst from π-Lewis acidity to σ-Lewis acidity

A cationic gold(I)-catalyzed decarboxylative etherification of propargyl carbonates to selectively produce propargyl ethers is reported. In the reaction the gold(I) catalyst shows a distinct σ-Lewis acidity rather than the commonly observed π-Lewis acidity, and thus catalyzes the decarboxylation of a variety of propargyl carbonates to give the corresponding propargyl ethers with high selectivity. This reaction represents a rare example of the tunable reactivity of cationic gold(I) complexes between σ-Lewis acidity and π-Lewis acidity.

TMSCl-mediated synthesis of α,β-unsaturated amides via C-C bond cleavage and C-N bond formation of propargyl alcohols with trimethylsilyl azide

A new method with high efficiency for the synthesis of α,β- unsaturated amides from the easily prepared propargyl alcohols and TMSN 3 using TMSCl as an acid promoter is developed. A wide variety of α,β-unsaturated amides were produced in moderate to excellent yields. Mechanistic studies indicate that this transformation involves TMSCl-mediated allenylazide intermediate formation, C-C bond cleavage, and C-N bond formation. Significantly, this reaction shows good functional group compatibility and high regioselectivity, with a relatively short reaction time and inexpensive reagents.