884010-16-6

Basic information

• Product Name: 2,2-dimethylpropane-1,3-diyl [2-bromophenyl] boronate
• Synonyms: 2,2-dimethylpropane-1,3-diyl [2-bromophenyl] boronate
• CAS NO: 884010-16-6
• Molecular Weight: 268.946
• Mol File: 884010-16-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2,2-dimethylpropane-1,3-diyl [2-bromophenyl] boronate(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-dimethylpropane-1,3-diyl [2-bromophenyl] boronate(884010-16-6)
• EPA Substance Registry System: 2,2-dimethylpropane-1,3-diyl [2-bromophenyl] boronate(884010-16-6)

Safety Data

• Hazardous Substances Data: 884010-16-6(Hazardous Substances Data)

Usage

General Description

2,2-dimethylpropane-1,3-diyl [2-bromophenyl] boronate is a chemical compound that is commonly used in organic synthesis and chemical research. It is a boronate ester, which means it contains a boron atom covalently bonded to two oxygen atoms and an alkyl or aryl group. This particular compound has a 2-bromophenyl group attached to the boron atom, making it useful for reactions involving arylboronic acids. It is often used as a reagent in the formation of carbon-carbon and carbon-heteroatom bonds, as well as in the synthesis of complex organic molecules. Its unique structure and versatile reactivity make it a valuable tool in the field of organic chemistry.

Upstream product

• 126-30-7 2,2-Dimethyl-1,3-propanediol 
• 244205-40-1 (2-bromophenyl)boronic acid 
• 668987-38-0 5,5-dimethyl-1,3,2-dioxaborinane 
• 583-53-9 2,3-dibromobenzene 

Downstream Products

• 884010-27-9 2,2-dimethylpropane-1,3-diyl [2-trimethylsilylethynylphenyl] boronate 
• 95-46-5 2-methylphenyl bromide 

Relevant articles and documents

Gold-Catalyzed Oxidative Biaryl Cross-Coupling of Organometallics

-

Copper-catalyzed cross-coupling reaction of organoboron compounds with primary alkyl halides and pseudohalides

Non-activated alkyl electrophiles, including alkyl iodides, bromides, tosylates, mesylates, and even chlorides, underwent copper-catalyzed cross-coupling with aryl boron compounds and alkyl 9-BBN reagents (see scheme; 9-BBN=9-borabicyclo[3.3.1]nonane). The reactions proceed with practically useful reactivities and thus complement palladium- and nickel-catalyzed Suzuki-Miyaura coupling reactions of alkyl halides.

Microwave-assisted synthesis of ethynylarylboronates for the construction of boronic acid-based fluorescent sensors for carbohydrates

A reliable and operationally simple procedure for the synthesis of 2,2-dimethylpropane-1,3-diyl ethynylaryl boronates 4 was developed. The key step is microwave-facilitated selective formation of 2,2-dimethylpropane-1,3-diyl trimethylsilylethynylaryl boro