884844-92-2

Upstream product

• 40798-40-1 2-iodo-3-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-henicosafluorodecyl)propyl acetate 
• 40798-36-5 3-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-henicosafluorodecyl)-propene 
• 423-62-1 1-Iodo-perfluorodecane 
• 114834-29-6 3-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-henicosafluorodecyl)-propane 1,2-diol 
• 1679-18-1 4-Chlorophenylboronic acid 

Downstream Products

• 2051-62-9 4'-biphenyl chloride 

Relevant academic research and scientific papers

The synthesis and application of fluorous boronates without perfluorinated solvents

The synthesis of a fluorous diol 4 bearing a perfluorodecyl chain was described. A series of boronic acid were attached to 4 by esterification. The purification of the products was fulfilled by facile filtration instead of expensive and environmental troublesome fluorous liquid-liquid extraction. The Suzuki cross-coupling reactions of the formed fluorous boronates 5 underwent smoothly and the fluorous diol 4 was recycled in good yields.