88511-99-3Relevant academic research and scientific papers
Direct Synthesis of Organobromogermanes from Methylenebromide
Schmidbaur, Hubert,Rott, Johann
, p. 285 - 287 (2007/10/02)
From the copper-catalyzed reaction of germanium powder with dibromomethane at 310 deg C a mixture of alkylbromogermanes is obtained.The major products are CH3GeBr3, Br3GeCH2Br (1), CH2(GeBr3)2 (2) and (CH2GeBr2)3 (3).The product distribution parallels the analogous reaction with dichloromethane reported previously.All compounds were characterized by analytical and spectroscopic data, and can be converted into the corresponding hydrides. - Keywords: Alkylbromogermanes, Synthesis, CVD Feeding Gas, Germanium/Copper Mixtures
Chemistry of Germanium Atoms. II. Reactions of Thermally Evaporated Germanium Vapor with Organic Halides
Mochida, Kunio,Tashiro, Kumiko,Yoshida, Yasuhiro,Mizuno, Yasuhisa
, p. 1247 - 1250 (2007/10/02)
Thermally generated germanium atoms were found to react with organic halides by insertion into carbon-halogen bonds.The resulting germylenes abstracted halogens from organic halides to form trihalogermyl derivatives.Tetrahalogermanes were also formed by t
The Reaction of Germanium Atoms with Organic Halides
Mochida, Kunio,Tashiro, Kumiko
, p. 1105 - 1108 (2007/10/02)
Co-condensation of thermally evaporated germanium vapor with organic halides yields a mixture of trihalogermyl derivatives and tetrahalogermanes as major products.The nature of these reactions is discussed.
