88536-51-0Relevant academic research and scientific papers
PHASE TRANSFER CATALYSIS AND HOMOGENEOUS REACTIONS WITH β-OXYALKYL RADICALS FROM ORGANOMERCURIALS
Barluenga, Jose,Lopez-Prado, Joaquin,Campos, Pedro J.,Asensio, Gregorio
, p. 2863 - 2868 (2007/10/02)
β-Alkoxy- and β-hydroxyalkyl radicals generated by sodium borohydride reduction of oxymercurials react with electron deficient olefins to give addition compounds in a homogeneous process.Heterogeneous reactions are also successful in the presence of catalytic amounts of surfactants and provide a superior method for the "one pot" reductive alkylation of oxymercurials.
