88546-75-2Relevant academic research and scientific papers
Polar bromination and chlorination of cyclopropane
Lambert, Joseph B.,Chelius, Erik C.,Schulz Jr., William J.,Carpenter, Nancy E.
, p. 3156 - 3162 (2007/10/02)
Cyclopropane has been prepared with three deuterium atoms on the same face (6, cyclopropane-cis-1,2,3-d3) in order to determine the mechanism of electrophilic halogenation. This labeling pattern permits determination of the stereochemistry of b
Stereochemical Kinetics of the Thermal Stereomutations Interconverting Achiral Isomers of 1-Phenyl-1,2,3-trideuteriocyclopropane
Baldwin, John E.,Patapoff, Thomas W.,Barden, Timothy C.
, p. 1421 - 1426 (2007/10/02)
All three achiral forms of 1-phenyl-1,2,3-trideuteriocyclopropane have been synthesized with high stereochemical integrity, and the thermal stereomutations among them have been followed at 309.3 deg C in the gas phase by Raman and 1H NMR spectroscopy.The
