885461-84-7Relevant academic research and scientific papers
Transition metal complexes of N1,N1,N2,N2-tetrakis(diphenylphosphaneyl)-ethane-1,2-diamine [(Ph2P)2NCH2CH2N(PPh2)2]
Kashid, Vitthalrao S.,Kote, Basvaraj S.,Kunchur, Harish S.,Mague, Joel T.,Balakrishna, Maravanji S.
, p. 87 - 94 (2019)
The reaction of ethylenediamine with four equivalents of chlorodiphenylphosphine in the presence of a base produced tetraphosphine [(Ph2P)2NCH2CH2N(PPh2)2] (1) which on further treatment wi
Synthesis and characterizations of N,N,N′,N′-tetrakis (diphenylphosphino)ethylendiamine derivatives: Use of palladium(II) complex as pre-catalyst in Suzuki coupling and Heck reactions
Akba, Osman,Durap, Feyyaz,Aydemir, Murat,Baysal, Akin,Gümgüm, Bahattin,?zkar, Saim
body text, p. 731 - 736 (2009/06/19)
Oxidation of N,N,N′,N′-tetrakis(diphenylphosphino)ethylendiamine (1) with elemental sulfur and selenium gives the corresponding sulfide and selenide, respectively, [(Ph2P(E))2NCH2CH2N(P(E)Ph 2)2] (E: S 1a, Se 1b). Complexes of 1 [(M2Cl4){(Ph2P)2NCH 2CH2N(PPh2)2}] (M: Ni(II) 1c, Pd(II) 1d, Pt(II) 1e) were prepared by the reaction of 1 with NiCl2 or [MCl2(COD)] (M = Pd, Pt). The new compounds were characterized by NMR, IR spectroscopy and elemental analysis. The catalytic activity of Pd(II) complex 1d was tested in the Suzuki coupling reaction and Heck reaction. The palladium complex 1d catalyses the Heck reaction between styrene and aryl bromides as well as Suzuki coupling reaction between phenylboronic acid and arylbromides affording stilbenes and biphenyls in high yield, respectively.
