88559-24-4

Upstream product

• 75-15-0 carbon disulfide 
• 24486-68-8 4-chlorophenacyl piperidine-1-carbodithioate 
• 74-88-4 methyl iodide 
• 88559-20-0 N,N-Dimethyl-dithiocarbaminsaeure-(4-chlor)-phenacylester 
• 91193-23-6 O-ethyl S-2-(4-chlorophenyl)-2-oxoethyl carbonodithioate 
• 119813-48-8 N-Phenyl-thiobenzimidic acid 2-(4-chloro-phenyl)-2-oxo-ethyl ester 
• 536-38-9 4-chlorobenzoylmethyl bromide 

Downstream Products

• 133616-73-6 4-(4-Chloro-benzoyl)-5-methylsulfanyl-[1,3]dithiol-2-one 

Relevant academic research and scientific papers

Synthesis of 1,3-Dithiol-2-thione Derivatives by Phase Transfer Dithiocarboxylation of CH-Acidic O-Alkyl Dithiocarbonates

CH-Acidic O-alkyl dithiocarbonates 1 react with carbon disulfide in a one-pot synthesis under basic conditions (NaH in DMF or phase transfer conditions) and S-alkylation to novel 1,3-dithiole-2-thiones 3-6.The structure of these compounds and supporting n.m.r., ir and mass spectra are discussed. - Keywords: 1,3-Dithiole-2-thiones; Dithiocarboxylation; O-Alkyl dithiocarbonates; Cyclocondensation; Phase transfer dithiocarboxylation; Carbon disulfide.

SYNTHESIS AND CRYSTAL STRUCTURE OF S-(1-BENZOYL-2-BIS-METHYLTHIO)-VINYL-PIPERIDINO-DITHIOCARBAMATE

The S-(1-benzoyl-2-bis-methylthio)vinyl-piperidino-dithiocarbamates 2a-d are prepared by dithiocarboxylation of phenacyl-piperidino-dithiocarbamates 1a-d under phase transfer conditions followed by methylation.In dry DMF and sodium hydride the reaction af