885622-42-4

Basic information

• Product Name: [(4-amino-2,2'-bipyridine)(acetonitrile)platinum(II)methyl][B(3,5-(CF₃)2C₆H₃)4]
• CAS NO: 885622-42-4
• Molecular Weight: 1285.59
• Mol File: 885622-42-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(4-amino-2,2'-bipyridine)(acetonitrile)platinum(II)methyl][B(3,5-(CF₃)2C₆H₃)4](CAS DataBase Reference)
• NIST Chemistry Reference: [(4-amino-2,2'-bipyridine)(acetonitrile)platinum(II)methyl][B(3,5-(CF₃)2C₆H₃)4](885622-42-4)
• EPA Substance Registry System: [(4-amino-2,2'-bipyridine)(acetonitrile)platinum(II)methyl][B(3,5-(CF₃)2C₆H₃)4](885622-42-4)

Safety Data

• Hazardous Substances Data: 885622-42-4(Hazardous Substances Data)

Upstream product

• 885622-36-6 4-amino-2,2'-bipyridineplatinum(II) dimethyl 
• 75-05-8 acetonitrile 
• 14151-21-4 [2,2’-bipyridine]-4-amine 

Relevant articles and documents

Protonation of platinum(II) dialkyl complexes containing ligands with proximate H-bonding substituents

The possibility of activating C-H bonds at a platinum(II) center that contains a ligand with a proximate H-bonding functionality, for example a NH2 substituent, has been investigated. A series of platinum(II) dimethyl complexes [Pt(L)Me2], where L is an unsymmetrically substituted bipyridine ligand, has been prepared. Protonation reactions in acetonitrile with 1 equiv of a strong acid generate cationic complexes of the type [Pt(L)Me(CH3CN)]+. The selectivity of the protonation reactions appears to be governed by steric effects rather than H-bonding effects. This is believed to be the result of the low basicity of the amino subsituent in 2-amino pyridines.