88613-62-1

Basic information

• Product Name: 2-(4'-N,N-dimethylaminophenyl)-thiophene
• Synonyms: 2-(4'-N,N-dimethylaminophenyl)-thiophene
• CAS NO: 88613-62-1
• Molecular Weight: 203.308
• Mol File: 88613-62-1.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: 2-(4'-N,N-dimethylaminophenyl)-thiophene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4'-N,N-dimethylaminophenyl)-thiophene(88613-62-1)
• EPA Substance Registry System: 2-(4'-N,N-dimethylaminophenyl)-thiophene(88613-62-1)

Safety Data

• Hazardous Substances Data: 88613-62-1(Hazardous Substances Data)

Upstream product

• 6165-68-0 thiophene boronic acid 
• 586-77-6 4-bromo-N,N-dimethylaniline 
• 188290-36-0 thiophene 
• 698-69-1 4-chloro-N,N-dimethylaniline 
• 96-43-5 2-thienyl chloride 
• 28611-39-4 4-(dimethylamino)benzene-boronic acid 
• 15106-95-3 bis(thien-2-yl)zinc 
• 1003-09-4 2-bromothiophene 
• 91511-88-5 p-(5-methyl-5-hydroxy-1,3-hexadiynyl)-N,N-dimethylaniline 

Downstream Products

• 130840-96-9 5-(4-(dimethylamino)cyclohexa-1,5-dien-1-yl)thiophene-2-carbaldehyde 
• 1056474-34-0 4,4,5,5-tetramethyl-2-(4-(thiophen-2-yl)phenyl)-1,3,2-dioxaborolane 
• 1098299-26-3 5-(4'-N,N-dimethylaminophenyl)-thiophene-2-sulfonyl chloride 
• 130841-00-8 (Z)-3-[5-(4-Dimethylamino-phenyl)-thiophen-2-yl]-2-(4-nitro-phenyl)-acrylonitrile 
• 130840-98-1 (E)-2-Benzenesulfonyl-3-[5-(4-dimethylamino-phenyl)-thiophen-2-yl]-acrylonitrile 
• 130841-01-9 {(E)-1-Cyano-2-[5-(4-dimethylamino-phenyl)-thiophen-2-yl]-vinyl}-phosphonic acid diethyl ester 
• 130840-99-2 Dimethyl-(4-{5-[(E)-2-(4-nitro-phenyl)-vinyl]-thiophen-2-yl}-phenyl)-amine 

Relevant articles and documents

Photoinduced Deaminative Borylation of Unreactive Aromatic Amines Enhanced by CO2

Herein, direct unreactive C-N borylation of aromatic amines by a photocatalyst was achieved. The C-N borylation of aromatic amines with bis(pinacolato)diboron (B2pin2) proceeded using a pyrene catalyst under light irradiation to afford desired borylated products and aminoborane as a byproduct. The yield of the borylated product improved under a CO2 atmosphere which probably reduced the inhibitory effect of aminoborane. Mechanistic studies suggested that the C-N bond cleavage and C-B bond formation proceeded via a concerted pathway.

Light-controlled reversible modulation of frontier molecular orbital energy levels in trifluoromethylated diarylethenes

Among bistable photochromic molecules, diarylethenes (DAEs) possess the distinct feature that upon photoisomerization they undergo a large modulation of their pelectronic system, accompanied by a marked shift of the HOMO/LUMO energies and hence oxidation/

Trisulfur radical anion as the key intermediate for the synthesis of thiophene via the interaction between elemental sulfur and NaO t Bu

A facile base-promoted sulfur-centered radical generation mode and a single-step protocol for the synthesis of thiophene derivatives using 1,3-diynes via the interaction between elemental sulfur and NaOtBu has been reported. EPR experiments revealed that the trisulfur radical anion acts as a key intermediate of this process. A plausible mechanism has been proposed.