88626-77-1Relevant academic research and scientific papers
ONE ELECTRON C-C BOND FORMING REACTIONS VIA ALLYLSTANNANES: SCOPE AND LIMITATIONS
Keck, Gary E.,Enholm, Eric J.,Yates, John B.,Wiley, Michael R.
, p. 4079 - 4094 (2007/10/02)
Free radical (or "one-electron") methodology for carbon-carbon bond forming reactions using allylstannanes is described in detail.Such reactions have the advantages of tolerating quite complex functionality in the substrate and of being nearly stoichiometric in reagents, and not requiring extensive experimentation for application to new substrates.
BASIC ELIMINATION OF SULFONIUM SALTS. NEIGHBOURING GROUP INFLUENCE ON REGIOSELECTIVITY.
Badet, B.,Julia, M.,Mallet, J. M.,Schmitz, C.
, p. 4331 - 4334 (2007/10/02)
A simple preparation of sulfonium salts functionalized by oxygenated groups is reported.The nature and the position of the latter control the regiochemistry of elimination of the sulfonium moiety leading to selective formation of Saytsev or Hofmann olefins.
