886359-03-1

Basic information

• Product Name: (2-[1',2',7':η-2'-(phenyl(tert-butyl)methylenephenyl)]pyrimidine-κN(1))tricarbonylmanganese(I)
• CAS NO: 886359-03-1
• Molecular Weight: 440.38
• Mol File: 886359-03-1.mol

Chemical Properties

• CAS DataBase Reference: (2-[1',2',7':η-2'-(phenyl(tert-butyl)methylenephenyl)]pyrimidine-κN(1))tricarbonylmanganese(I)(CAS DataBase Reference)
• NIST Chemistry Reference: (2-[1',2',7':η-2'-(phenyl(tert-butyl)methylenephenyl)]pyrimidine-κN(1))tricarbonylmanganese(I)(886359-03-1)
• EPA Substance Registry System: (2-[1',2',7':η-2'-(phenyl(tert-butyl)methylenephenyl)]pyrimidine-κN(1))tricarbonylmanganese(I)(886359-03-1)

Safety Data

• Hazardous Substances Data: 886359-03-1(Hazardous Substances Data)

Upstream product

• 75-09-2 dichloromethane 
• 748802-52-0 [2-(phenyl-κC2',κC2'')pyrimidine-(κN1,κN2)]bis(tetracarbonylmanganese(I)) 
• 83922-79-6 (1-diazo-2,2-dimethylpropyl)benzene 

Relevant articles and documents

New manganese-scaffolded organic triple-deckers based on quinoxaline, pyrazine and pyrimidine cores

The thermolytic coupling of Ph2CN2 and (t-Bu)(Ph)CN2 with doubly cyclomanganated 2,5-diphenylpyrazine and 4,6-diphenylpyrimidine afforded substantial amounts of new triple decker compounds of either Ci and C2 symmetry respectively containing, in both series, two η3-bonded Mn(CO)3 fragments which intervene as scaffolds sustaining the helical non-conjugated triaryl backbone. The molecular structures of two pyrazine derivatives show a typical non-parallel stacking of the aromatic rings and the encapsulation of the central pyrazyl fragment with interplanar centroid-to-centroid distances of ca. 3.5 . The stacking of the aromatics in the triple-decker pyrimidine derivatives has been assessed by 1H NMR experiments at low temperature. All the triple-decker-type compounds are electroactive. Pyrimidine triple-deckers can reversibly be electrochemically reduced to the corresponding anions. The Royal Society of Chemistry 2006.