886368-32-7

Upstream product

• 19432-96-3 3-(phenylsulfonyl)propyl chloride 
• 108-98-5 thiophenol 
• 3238-98-0 3-phenylthio-1-bromopropane 
• 873-55-2 sodium benzenesulfonate 

Downstream Products

• 1228297-55-9 3-chloro-1-phenylsulfonyl-3-(phenylthio)propane 
• 886368-17-8 {2-[6-(2-benzenesulfonyl-ethyl)-6-methoxy-5,6-dihydro-2H-pyran-2-yl]-ethoxy}-tert-butyl-diphenyl-silane 
• 886368-96-3 tert-butyl-{2-[6-methoxy-6-(2-phenylsulfanyl-ethyl)-5,6-dihydro-2H-pyran-2-yl]-ethoxy}-diphenyl-silane 

Relevant academic research and scientific papers

Synthesis of substituted tetrahydrofurans via intermolecular reactions of γ-chlorocarbanions of 3-substituted 3-chloro-propylphenyl sulfones with aldehydes

Carbanions of 3-substituted-3-chloropropyl phenyl sulfones add to carbonyl groups of aldehydes to produce aldol type adducts that undergo 1,5-intramolecular substitution giving 2,3,5-trisubstituted tetrahydrofurans. The effect of substituents in the 3-pos

Synthesis of the C1-C26 northern portion of azaspiracid-1: Kinetic versus thermodynamic control of the formation of the bis-spiroketal

North-South divide: An efficient synthesis of the entire C1-C26 (northern) portion of azaspiracid-1 is disclosed (see picture). Key transformations include the formation of a bis-spiroketal, the oxidation of a sulfone at C10 to form a β,γ-unsaturated keto