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Room temperature palladium-catalyzed intramolecular hydroamination of unactivated alkenes
Michael, Forrest E.,Cochran, Brian M.
, p. 4246 - 4247 (2007/10/03)
A mild and facile Pd-catalyzed intramolecular hydroamination of unactivated alkenes is described. This reaction takes place at room temperature and is tolerant of synthetically useful acid-sensitive functional groups. The formation of hydroamination products rather than oxidative amination products is due to the use of a tridentate ligand on Pd which effectively inhibits β-hydride elimination. Copyright
