886595-31-9Relevant articles and documents
Synthesis of fluoroalkyl palladium and nickel complexes via decarbonylation of acylmetal species
Maleckis, Ansis,Sanford, Melanie S.
, p. 3831 - 3839 (2014)
The synthesis and characterization of a series of fluoroalkyl palladium(II) and nickel(II) complexes via decarbonylation of the corresponding acylmetal species is reported. At palladium(II), labile supporting ligands such as tri-o-tolylphosphine are required to achieve decarbonylation within 30 min at 85 °C. In contrast, decarbonylation at (PPh3)2Ni(C(O) RF)(OCORF) (RF = fluoroalkyl) complexes proceeds rapidly at or below room temperature.