886848-91-5Relevant academic research and scientific papers
Synthesis and crystal structure analysis of ferrocenylthiosemicarbazone complexes of palladium(II): Unusual σpd-C bond cleavage
Mari?o, Marta,Gayoso, Eduardo,Antelo, José M.,Adrio, Luis A.,Fernández, Jesús J.,Vila, José M.
, p. 1449 - 1456 (2008/10/09)
The reaction of the thiosemicarbazones (η5-C 5H5)Fe(η5-C5H 4)C(H)NN(H)C(S)NHR (R = H, a; R = Me, b) with K2PdCl 4 afforded octanuclear cyclometallated complexes [Pd{(η 5-C5H5)Fe(η5-C5H 3)C(H)NNC(S)NHR}]4 (R = H, 1a; R = Me, 1b). Reaction of complexes 1a and 1b with tertiary diphosphines in 1:2 molar ratio and subsequent recrystallization from CH2Cl2/n-C6H 14 gave rise to tetranuclear complexes [{Pd[(η5-C 5H5)Fe(η5-C5H 4)C(H)NNC(S)NHR](Cl)}2(μ-Ph2P(CH 2)nPPh2)] (R = H, n = 4, 2a; R = Me, n = 1, 2b; n = 4, 3b). Treatment of complexes 1a and 1b with tertiary monophosphines in 1:4 molar ratio and subsequent recrystallization from CH2Cl 2/n-C6H14 gave rise to dinuclear complexes [Pd{(η5-C5H5)Fe(η5-C 5H4)C(H)NNC(S)-NHR}(Cl)(P)] (R = H: P = PPh3, 3a; P = PPh2Et, 4a; P = P(C6D5)3, 5a; R = Me: P = PPh3, 4b; P = PPh2Et, 5b; P = P(C 6D5)3, 6b). The crystal structures of 2a and 2b have been determined by X-ray crystallography.
