24762-44-5

Basic information

• Product Name: TRI(PHENYL-D5)PHOSPHINE
• Synonyms: TRIPHENYLPHOSPHINE-D15;TRI(PHENYL-D5)PHOSPHINE;TRI(PHENYL-D5)PHOSPHINE, 99 ATOM % D;tris(2,3,4,5,6-pentadeuteriophenyl)phosphane
• CAS NO: 24762-44-5
• Molecular Formula: C₁₈H₁₅P
• Molecular Weight: 277.38
• Product Categories: Alphabetical Listings;Stable Isotopes
• Mol File: 24762-44-5.mol
• Article Data: 3

Chemical Properties

• Melting Point: 78-80 °C(lit.)
• Boiling Point: 377 °C
• Flash Point: 220℃
• Appearance: /
• Storage Temp.: Room Temperature
• Solubility: Chloroform (Slightly), Hexanes (Slightly)
• CAS DataBase Reference: TRI(PHENYL-D5)PHOSPHINE(CAS DataBase Reference)
• NIST Chemistry Reference: TRI(PHENYL-D5)PHOSPHINE(24762-44-5)
• EPA Substance Registry System: TRI(PHENYL-D5)PHOSPHINE(24762-44-5)

Safety Data

• Hazard Codes: Xn,N
• Statements: 20/21/22-36/37/38-50/53
• Safety Statements: 45-61-60
• RIDADR: UN 3077 9 / PGIII
• WGK Germany: 3
• Hazardous Substances Data: 24762-44-5(Hazardous Substances Data)

Usage

Uses

Different sources of media describe the Uses of 24762-44-5 differently. You can refer to the following data:
1. Triphenylphosphine-d15 is the labelled version of Triphenylphosphine (T808975) which is used in the synthesis of Chlorambucil with cytotoxicity in breast and pancreatic cancers. Triphenylphosphine is also used in the preparation of α-Tocopherol analogues for monitoring antioxidant status.
2. Employed in a mechanistic study of cis-bis(silylmethyl)platinum(II) complexes.

Upstream product

• 4165-57-5 bromobenzene-d5 
• 1076-43-3 benzene-d6 
• 7379-67-1 d₅-iodobenzene 

Downstream Products

• 72142-99-5 bis-pentadeuteriophenyl-phosphane 
• 1610606-42-2 C₂₆H₇⁽²⁾H₁₅AuF₃IP 
• 1610606-41-1 C₂₅H₄⁽²⁾H₁₅AuF₄IP 
• 1259387-50-2 trans-[Pd(C₆H₄O-2-(C₆H₅O₂))I(P(C₆D₅)3)2] 
• 1158081-71-0 [⁽²⁾H₁₀]-2-(diphenylphosphino)benzoic acid 
• 886848-96-0 [[Pd[(η(5)-C5H5)Fe(η(5)-C5H4)C(H)=NN=C(S)NHCH3](Cl)(P(C6D5)3] 
• 886848-91-5 [[Pd[(η(5)-C5H5)Fe(η(5)-C5H4)C(H)=NN=C(S)NH2](Cl)(P(C6D5)3] 
• 38122-34-8 dichlorobis(triphenylphosphine-d15)platinum 
• 709-63-7 1-(4-trifluoromethylphenyl)ethanone 
• 2043-61-0 cyclohexanecarbaldehyde 
• 100-06-1 1-(4-methoxyphenyl)ethanone 

Relevant articles and documents

[ReF6]2-: A robust module for the design of molecule-based magnetic materials

A facile synthesis of the [ReF6]2- ion and its use as a building block to synthesize magnetic systems are reported. Using dc and ac magnetic susceptibility measurements, INS and EPR spectroscopies, the magnetic properties of the isolated [ReF6]2- unit in (PPh4)2[ReF6]?2H2O (1) have been fully studied including the slow relaxation of the magnetization observed below ca. 4 K. This slow dynamic is preserved for the one-dimensional coordination polymer [Zn(viz)4(ReF 6)]1 (2, viz=1-vinylimidazole), demonstrating the irrelevance of low symmetry for such magnetization dynamics in systems with easy-plane-type anisotropy. The ability of fluoride to mediate significant exchange interactions is exemplified by the isostructural [Ni(viz)4(ReF6)]1 (3) analogue in which the ferromagnetic NiII-ReIV interaction (+10.8 cm-1) dwarfs the coupling present in related cyanide-bridged systems. These results reveal [ReF6]2- to be an unique new module for the design of molecule-based magnetic materials.

Sequestered alkyllithiums: Why phenyllithium alone is suitable for betaine-ylide generation

The key step in the trans-selective modification of the Wittig reaction is the α-lithiation of the lithium bromide coordinated ylide - aldehyde adduct (the so-called "P-betaine"). Only phenyllithium effects this deprotonation rapidly and cleanly. Alkyllithiums (in particular, butyl-, sec-butyl-, and tert-butyllithium) react only sluggishly and incompletely, being tied up in very stable mixed aggregates with the lithium alkoxide part of the betaines.