886982-13-4Relevant academic research and scientific papers
Activation of dichloromethane by a V(iii) thiolate complex: An example of S-based nucleophilic reactivity in an early transition metal thiolate
Chen, Tzu-Tso,Chen, Yu-Sen,Chang, Ya-Ho,Wang, Jung-Ching,Tsai, Yi-Fang,Lee, Gene-Hsiang,Kuo, Tin-Shen,Hsu, Hua-Fen
, p. 1109 - 1111 (2013)
A VIII thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a VIII-Cl species (major one) and a VIV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.
Catalytic reduction of hydrazine to ammonia by a vanadium thiolate complex
Chu, Wei-Cheng,Wu, Chi-Chin,Hsu, Hua-Fen
, p. 3164 - 3166 (2008/10/09)
Vanadium(III) thiolate complexes, [V(PS3″)(Cl)]- [1a; PS3″ = P(C6H3-3-Me3Si-2-S) 33-] and [V(PS3′)(Cl)]- [1b; PS3′ = P(C6H3-5-Me-2-S)33-], were synthesized and characterized. Complex 1a serves as a precursor for the catalytic reduction of hydrazine to ammonia. The spectroscopic and electrochemical studies indicate that hydrazine is bound and activated in a VII state.
