88710-69-4Relevant academic research and scientific papers
Highly efficient 1,4-addition of 1,3-diesters to conjugated enones by In/TMSCl
Lee, Phil Ho,Seomoon, Dong,Lee, Kooyeon,Heo, Yunkiu
, p. 2510 - 2513 (2007/10/03)
Organoindium reagents derived from indium and diethyl bromomalonates were added to a wide range of conjugated enones in a 1,4-fashion in the presence of TMSCl under mild conditions, and corresponding oxo-1,3-diesters were obtained in good to excellent yields.
ORGANIC REACTIONS AT HIGH PRESSURE. MICHAEL ADDITION OF ACTIVATED ACYCLIC DONORS WITH β,β-DISUBSTITUTED ENONE ACCEPTORS.
Dauben, William G.,Gerdes, John M.
, p. 3841 - 3844 (2007/10/02)
High pressure, 15 kbar (1.5 GPa) Michael additions of doubly activated acyclic donors to sterically hindered enone acceptors with 1,5-diazabicyclonon-5-ene in acetonitrile affords Michael adducts in 42-82percent yield.
