88727-39-3Relevant academic research and scientific papers
THE REACTIONS OF ACETONE AND OF DIACETONE ALCOHOL WITH (NO)I2>. THE FORMATION OF (NO)I(OET)> AND THE STRUCTURES OF (NO)I2O> AND A BICYCLIC SALT
Adams, Harry,Bailey, Neil A.,Denti, Gianfranco,McCleverty, Jon A.,Smith, John M. A.,Wlodarczyk, Andrej
, p. 2287 - 2292 (1983)
The complex (NO)I2> (Me2pz=3,5-dimethylpyrazolyl) reacted with boiling acetone and with diacetone alcohol (4-hydroxy-4-methyl-2-pentanone) over several days, giving low yields of the salt of the cation (1+), (NO)I>2O>, and (NO)I(OEt)>.The structure of an iodide salt of the organic cation, and of the bimetallic species have been determined crystallographically.The organic salt is a bicyclic species derived by fusion of a C3 fragment (possibly derived from diacetone alcohol) across the N-N bond of 3,5-dimethylpyrazole.The bimetallic species can be described as two distorted, eclipsed octahedra sharing the bridging O atom, where the Mo-O distances are 1.86 and 1.93 Angstoem, and the Mo-O-Mo angle is 171 deg.Possible routes to the formation of these compounds are discussed.
