THE REACTIONS OF ACETONE AND OF DIACETONE ALCOHOL WITH (NO)I2>. THE FORMATION OF (NO)I(OET)> AND THE STRUCTURES OF (NO)I2O> AND A BICYCLIC SALT

DOI: 10.1039/DT9830002287

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2287 - 2292 (1983)

Update date:2022-08-03

Topics:

Authors:

Adams, Harry

Bailey, Neil A.

Denti, Gianfranco

McCleverty, Jon A.

Smith, John M. A.

Wlodarczyk, Andrej

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9830002287

The complex (NO)I2> (Me2pz=3,5-dimethylpyrazolyl) reacted with boiling acetone and with diacetone alcohol (4-hydroxy-4-methyl-2-pentanone) over several days, giving low yields of the salt of the cation (1+), <(NO)I>2O>, and (NO)I(OEt)>.The structure of an iodide salt of the organic cation, and of the bimetallic species have been determined crystallographically.The organic salt is a bicyclic species derived by fusion of a C3 fragment (possibly derived from diacetone alcohol) across the N-N bond of 3,5-dimethylpyrazole.The bimetallic species can be described as two distorted, eclipsed octahedra sharing the bridging O atom, where the Mo-O distances are 1.86 and 1.93 Angstoem, and the Mo-O-Mo angle is 171 deg.Possible routes to the formation of these compounds are discussed.

Full text of DOI:10.1039/DT9830002287

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2C₁₁H₁₉N₂O⁽¹⁺⁾*I₃^(1-)*I^(1-)

Cas No:88727-39-3

R&D Labs maybe for 88727-39-3

Guangxi Nanning Guangtai Agriculture Chemical Co.,Ltd

Contact:+86-771-2311266

Address:Room703,Building12, Software Park Phase II,NO.68,Keyuan Road,Nanning City,Guangxi,China
Allright GC (Jinan) Biotechnology Ltd.

website:https://www.argcbiotech.com/

Contact:86-18405413579-

Address: No.27566 of Jingshiroad, Huaiyin District, Jinan City(250011), Shandong Province, China.
RongCheng K&S Chemical Co.,Ltd

Contact:0631-7336369

Address:rongcheng ,shandong province china
Chengdu Chengnuo New-Tech Co., Ltd

Contact:0086-028-85749078

Address:4 Jiuyang road,Jiulong industrial port,Chengdu, China
Wuxi Zuping Food Science And Technology Co.,LTD.

Contact:+86-510-87210822

Address:Guanlin town

Relevant to this article

Temperature-dependent coordination of phosphine to five-coordinate alkenylruthenium complexes

Doi:10.1021/ic061389f
(2007)
Highly regioselective Friedel-Crafts reactions of electron-rich aromatic compounds with pyruvate catalyzed by Lewis acid-base: Efficient synthesis of pesticide cycloprothrin

Doi:10.1002/adsc.200505450
(2006)
An Annelation Approach to the Synthesis of Eudesmane and Elemane Sesquiterpene Lactones. Total Synthesis of dl-Dihydrocallitrisin, dl-7,8-Epialantolactone, dl-7,8-Epiisoalantolactone, and dl-Atractylon

Doi:10.1021/ja00527a046
(1980)
Synthesis of an ambergris-type ketal from abietic acid

Doi:10.1055/s-2006-926392
(2006)
Controlling the oxidation state of arsenic in cyclic arsenic cations

Doi:10.1039/b602017h
(2006)
STUDIES ON THE beta -TURN OF PEPTIDES. IV. EFFECT OF THE CHAIN LENGTH ON THE CD SPECTRA OF N-(2,4-DINITROPHENYL)-(GLY)_n-_D-Ala-_L-Pro-(GLY)_n P-NITROANILIDES (n equals 1 minus 3).

Doi:10.1246/bcsj.56.2476
(1983)

Article Doi