THE REACTIONS OF ACETONE AND OF DIACETONE ALCOHOL WITH (NO)I2>. THE FORMATION OF (NO)I(OET)> AND THE STRUCTURES OF (NO)I2O> AND A BICYCLIC SALT

DOI: 10.1039/DT9830002287

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2287 - 2292 (1983)

Update date:2022-08-03

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Authors:

Adams, Harry

Bailey, Neil A.

Denti, Gianfranco

McCleverty, Jon A.

Smith, John M. A.

Wlodarczyk, Andrej

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Article abstract of DOI:10.1039/DT9830002287

The complex (NO)I2> (Me2pz=3,5-dimethylpyrazolyl) reacted with boiling acetone and with diacetone alcohol (4-hydroxy-4-methyl-2-pentanone) over several days, giving low yields of the salt of the cation (1+), <(NO)I>2O>, and (NO)I(OEt)>.The structure of an iodide salt of the organic cation, and of the bimetallic species have been determined crystallographically.The organic salt is a bicyclic species derived by fusion of a C3 fragment (possibly derived from diacetone alcohol) across the N-N bond of 3,5-dimethylpyrazole.The bimetallic species can be described as two distorted, eclipsed octahedra sharing the bridging O atom, where the Mo-O distances are 1.86 and 1.93 Angstoem, and the Mo-O-Mo angle is 171 deg.Possible routes to the formation of these compounds are discussed.

Full text of DOI:10.1039/DT9830002287

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