887404-52-6Relevant academic research and scientific papers
An efficient protocol for the enantioselective preparation of a key polyfunctionalized cyclohexane. New access to (R)- and (S)-4-hydroxy-2- cyclohexenone and (R)- and (S)-trans-cyclohex-2-ene-1,4-diol
Bayon, Pau,Marjanet, Georgina,Toribio, Gladis,Alibes, Ramon,De March, Pere,Figueredo, Marta,Font, Josep
, p. 3486 - 3491 (2008/09/21)
(Chemical Equation Presented) Starting from very accessible raw materials such as p-methoxyphenol, ethylene glycol, and thiophenol, a protocol has been developed to prepare multigram quantities of the polyfunctionalized cyclohexane (±)-7. A highly efficie
Enantioselective synthesis and absolute configuration assignment of gabosine O. synthesis of (+)- and (-)-gabosine N and (+)- and (-)-epigabosines N and O
Alibes, Ramon,Bayon, Pau,De March, Pedro,Figueredo, Marta,Font, Josep,Marjanet, Georgina
, p. 1617 - 1620 (2007/10/03)
A rational approach to the synthesis of gabosines and other related carba-sugars starting from a masked p-benzoquinone has been designed. The enantioselective acetylation of the hydroxyketal 2 provides a practical entry to either enantiomer of the target
