88754-10-3Relevant academic research and scientific papers
Catalytic Radical-Polar Crossover Reactions of Allylic Alcohols
Touney, Eric E.,Foy, Nicholas J.,Pronin, Sergey V.
supporting information, p. 16982 - 16987 (2018/12/14)
Radical-polar crossover hydrofunctionalizations of tertiary allylic alcohols are described. Depending on the structure of the catalyst, corresponding epoxides or semipinacol rearrangement products are selectively obtained in good yields. Experimental evidence points to the participation of alkylcobalt complexes as electrophilic intermediates.
STEREOSPECIFIC SYNTHESES AND REACTIONS OF ALLYL- AND ALLENYL-SILANES
Fleming, Ian,Terrett, Nicholas K.
, p. 99 - 118 (2007/10/02)
The stereospecifically anti synthesis of allyl- and allenyl-silanes by the reaction of a silylcuprate reagent with allyl and propargyl acetates is described.The SE2' reactions of these silanes with various electrophiles are shown to proceed wit
THE STEREOCHEMISTRY OF SOME SE2' REACTIONS OF ALLYL- AND ALLENYLSILANES
Fleming, Ian,Terrett, Nicholas K.
, p. 4153 - 4156 (2007/10/02)
The SE2' reactions of 1 and 2 with a range of electrophiles are predominantly anti in the allylsilane portion of the molecule, but this offset, to a greater or lesser extent, by axial or equatorial preferences in the ring system.
