91621-60-2Relevant academic research and scientific papers
Palladium-catalyzed asymmetric synthesis of axially chiral molecules
Fiaud, J. C.,Legros, J. Y.
, p. 383 - 396 (2007/10/02)
The asymmetric synthesis of chiral 3-alkylidene bicyclooctane and 4-substituted 1-alkylidene cyclohexane systems has been carried out (in up to 40percent ee) by the palladium-catalyzed reaction of allylic acetates with sodium dimethyl malonate or m
STEREOSPECIFIC SYNTHESES AND REACTIONS OF ALLYL- AND ALLENYL-SILANES
Fleming, Ian,Terrett, Nicholas K.
, p. 99 - 118 (2007/10/02)
The stereospecifically anti synthesis of allyl- and allenyl-silanes by the reaction of a silylcuprate reagent with allyl and propargyl acetates is described.The SE2' reactions of these silanes with various electrophiles are shown to proceed wit
