88769-09-9Relevant academic research and scientific papers
DIRECTED ORTHO METALATION OF SILYLOXYBENZAMIDES. ANION INDUCED O C SILICON REARRANGEMENT
Billedeau, R.J.,Sibi, M.P.,Snieckus, V.
, p. 4515 - 4518 (1983)
Trialkylsilyloxybenzamides 4, o- and m-OSiR3 undergo directed ortho metalation-mediated silicon rearrangement to salicylamides 6, 6- and 3-OH by intra- and inter-molecular mechanisms respectively.
