DIRECTED ORTHO METALATION OF SILYLOXYBENZAMIDES. ANION INDUCED O C SILICON REARRANGEMENT

DOI: 10.1016/S0040-4039(00)85942-0

Source and publish data:

Tetrahedron Letters p. 4515 - 4518 (1983)

Update date:2022-07-31

Topics:

Authors:

Billedeau, R.J.

Sibi, M.P.

Snieckus, V.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)85942-0

Trialkylsilyloxybenzamides 4, o- and m-OSiR₃ undergo directed ortho metalation-mediated silicon rearrangement to salicylamides 6, 6- and 3-OH by intra- and inter-molecular mechanisms respectively.

Full text of DOI:10.1016/S0040-4039(00)85942-0

Products guided by the article

Product name:Benzamide, N,N-diethyl-2-hydroxy-6-(trimethylsilyl)-

Cas No:88769-09-9

R&D Labs maybe for 88769-09-9

Jining tiansheng chemical co.,ltd.

Contact:+86-537-5158722

Address:ROOM 1011, BLOCK B, CUIDU INTERNATIOAL BUSINESS CENTER, JINING CITY, CHINA
Taizhou Green Peptide Trading Co., Ltd.

Contact:--

Address:Room 1501, No71, Yuehe Road, Taizhou City, Zhejiang Province, China
Shuanghe Bio-Technology Limited(expird)

Contact:+86-571-61710758,18968016640

Address:Jinqiao north road 916# Fuyang
Molobelamltrading

Contact:27-792-602929

Address:SIDNEY MUFAMADI STREET 009949 X44 0700 POLOKWANE,LIMPOPO
Guangxi Bonger Pharmaceutical Co., Ltd

website:http://napo.lookchem.com/

Contact:+86-18817331185

Address:Donghai Industrial Zone, Tiandong Country,Guangxi,China

Relevant to this article

Synthesis of saponins with cholestanol, cholesterol, and friedelanol as aglycones

Doi:10.1002/ejoc.200500816
(2006)
Total synthesis and stereochemical reassignment of (+)-dolastatin 19

Doi:10.1021/ol060609q
(2006)
A diastereoselective radical cyclization approach to substituted quinuclidines

Doi:10.1021/jo060349q
(2006)
Regioselective monoacetylation of methyl pyranosides of pentoses and 6-deoxyhexoses by acetic anhydride in the presence of MoCl₅

Doi:10.1080/00397910600591565
(2006)
Synthesis of 3-indolylmethyl substituted (pyrazolo/benzo)triazinone derivatives under Pd/Cu-catalysis: Identification of potent inhibitors of chorismate mutase (CM)

Doi:10.1016/j.bioorg.2019.103155
(2019)
Doi:10.1021/ja01607a080
(1955)

Article Doi