DIRECTED ORTHO METALATION OF SILYLOXYBENZAMIDES. ANION INDUCED O C SILICON REARRANGEMENT

DOI: 10.1016/S0040-4039(00)85942-0

Source and publish data:

Tetrahedron Letters p. 4515 - 4518 (1983)

Update date:2022-07-31

Topics:

Authors:

Billedeau, R.J.

Sibi, M.P.

Snieckus, V.

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Article abstract of DOI:10.1016/S0040-4039(00)85942-0

Trialkylsilyloxybenzamides 4, o- and m-OSiR₃ undergo directed ortho metalation-mediated silicon rearrangement to salicylamides 6, 6- and 3-OH by intra- and inter-molecular mechanisms respectively.

Full text of DOI:10.1016/S0040-4039(00)85942-0

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