88769-13-5Relevant academic research and scientific papers
Enantioselective synthesis of the dimeric pyranonaphthoquinone core of the cardinalins using a late-stage homocoupling strategy
Sperry, Jonathan,Gibson, Jennifer S.,Sejberg, Jimmy J. P.,Brimble, Margaret A.
supporting information; experimental part, p. 4261 - 4270 (2009/02/07)
The enantioselective synthesis of a dimeric pyranonaphthoquinone closely related to the cardinalins is described. Whilst attempts to effect a double Hauser-Kraus annulation of enone 5 were unsuccessful using both bis-phthalide 4 and bis-sulfone 21, a sing
DIRECTED ORTHO METALATION OF SILYLOXYBENZAMIDES. ANION INDUCED O C SILICON REARRANGEMENT
Billedeau, R.J.,Sibi, M.P.,Snieckus, V.
, p. 4515 - 4518 (2007/10/02)
Trialkylsilyloxybenzamides 4, o- and m-OSiR3 undergo directed ortho metalation-mediated silicon rearrangement to salicylamides 6, 6- and 3-OH by intra- and inter-molecular mechanisms respectively.
