887699-73-2

Basic information

• Product Name: triethyl 2-(2-iodophenyl)orthoacetate
• Synonyms: triethyl 2-(2-iodophenyl)orthoacetate
• CAS NO: 887699-73-2
• Molecular Weight: 364.223
• Mol File: 887699-73-2.mol

Chemical Properties

• CAS DataBase Reference: triethyl 2-(2-iodophenyl)orthoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: triethyl 2-(2-iodophenyl)orthoacetate(887699-73-2)
• EPA Substance Registry System: triethyl 2-(2-iodophenyl)orthoacetate(887699-73-2)

Safety Data

• Hazardous Substances Data: 887699-73-2(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 40400-15-5 2-(2-iodophenyl)acetonitrile 

Downstream Products

• 902751-35-3 methyl 2,7-di-O-benzyl-N-O-(2-cyanophenyl)acetyl-6-deoxy-glycero-β-D-manno-heptopyranosyl-(1->4)-2,3-O-isopropylidene-α-L-rhamnopyranoside 
• 902751-33-1 methyl 2,7-di-O-benzyl-4,6-O-{1-cyano-2-(2-iodophenyl)ethylidene}-D-glycero-β-D-manno-heptopyranosyl-(1->4)-2,3-O-isopropylidene-α-L-rhamnopyranoside 
• 902751-32-0 methyl 2,7-di-O-benzyl-4,6-O-{1-cyano-2-(2-iodophenyl)ethylidene}-3-O-(2-naphthalenylmethyl)-D-glycero-β-D-manno-heptopyranosyl-(1->4)-2,3-O-isopropylidene-α-L-rhamnopyranoside 
• 902751-36-4 methyl 2,7-di-O-benzyl-4,6-O-benzylidene-D-glycero-β-D-manno-heptopyranosyl-(1->3)-2,7-di-O-benzyl-4-O-(2-cyanophenyl)acetyl-6-deoxy-glycero-β-D-manno-heptopyranosyl-(1->4)-2,3-O-isopropylidene-α-L-rhamnopyranoside 
• 887699-95-8 methyl 2,3,6-tri-O-benzyl-4-O-(2,3-di-O-benzoyl-4,6-O-[1-cyano-2-(2-iodophenyl)]ethylidene-β-D-galactopyranosyl)-α-D-glucopyranoside 
• 887699-94-7 methyl 2,3,4-tri-O-benzyl-6-O-(2,3-di-O-benzoyl-4,6-O-[1-cyano-2-(2-iodophenyl)]ethylidene-β-D-galactopyranosyl)-α-D-glucopyranoside 
• 887699-88-9 methyl 2,3,4-tri-O-benzyl-6-O-(2,3-di-O-benzyl-4,6-O-[1-cyano-2-(2-iodophenyl)]ethylidene-β-D-mannopyranosyl)-α-D-glucopyranoside 

Relevant articles and documents

4,6-O-[1-cyano-2-(2-iodophenyl)ethylidene] acetals. Improved second-generation acetals for the stereoselective formation of β-D-mannopyranosides and regioselective reductive radical fragmentation to β-D-rhamnopyranosides. Scope and limitations

The [1-cyano-2-(2-iodophenyl)]ethylidene group is introduced as an acetal-protecting group for carbohydrate thioglycoside donors. The group is easily introduced under mild conditions, over short reaction times, and in the presence of a wide variety of oth