887769-14-4

Basic information

• Product Name: (2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-12-(tert-butyl-diphenyl-silanyloxy)-6-methyl-6-triethylsilanyloxy-dodecane-1,2,3-triol
• Synonyms: (2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-12-(tert-butyl-diphenyl-silanyloxy)-6-methyl-6-triethylsilanyloxy-dodecane-1,2,3-triol
• CAS NO: 887769-14-4
• Molecular Weight: 829.277
• Mol File: 887769-14-4.mol

Chemical Properties

• CAS DataBase Reference: (2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-12-(tert-butyl-diphenyl-silanyloxy)-6-methyl-6-triethylsilanyloxy-dodecane-1,2,3-triol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-12-(tert-butyl-diphenyl-silanyloxy)-6-methyl-6-triethylsilanyloxy-dodecane-1,2,3-triol(887769-14-4)
• EPA Substance Registry System: (2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-12-(tert-butyl-diphenyl-silanyloxy)-6-methyl-6-triethylsilanyloxy-dodecane-1,2,3-triol(887769-14-4)

Safety Data

• Hazardous Substances Data: 887769-14-4(Hazardous Substances Data)

Upstream product

• 81255-14-3 methyl 2,3-di-O-benzyl-4-C-methyl-α-D-glucopyranoside 
• 887768-96-9 methyl 2,3-di-O-benzyl-6-iodo-4-C-methyl-α-D-glucopyranoside 
• 864712-70-9 (2S,3S,4S,5R,6R)-methyl 4,5-bis(benzyloxy)-12-t-butyldiphenylsiloxy-6-triethylsiloxy-2,3-dihydroxy-6-methyldodecanoate 
• 887769-11-1 C₅₃H₈₂O₅Si₃ 
• 887768-95-8 (E,4S,5R,6R)-methyl 4,5-bis(benzyloxy)-12-t-butyldiphenylsiloxy-6-triethylsiloxy-6-methyldodec-2-enoate 
• 864712-67-4 (2R,3R,4R)-2,3-bis(benzyloxy)-10-t-butyldiphenylsiloxy-4-triethylsiloxy-4-methyldecanal 
• 887768-97-0 (2S,3R,4R)-2,3-bis(benzyloxy)-10-t-butyldiphenylsiloxy-4-methyldecane-1,4-diol 
• 864712-69-6 {6-[3,4-bis(benzyloxy)tetrahydro-5-methoxy-2-methylfuran-2-yl]hexyloxy}(t-butyl)diphenylsilane 
• 864712-68-5 3,4-bis(benzyloxy)tetrahydro-5-methoxy-2-methyl-2-vinylfuran 
• 887769-10-0 [(E)-6-((2R,3R,4R)-3,4-Bis-benzyloxy-5-methoxy-2-methyl-tetrahydro-furan-2-yl)-hex-4-enyloxy]-tert-butyl-diphenyl-silane 
• 887769-08-6 2-((2R,3R,4R)-3,4-Bis-benzyloxy-5-methoxy-2-methyl-tetrahydro-furan-2-yl)-ethanol 
• 887769-09-7 ((2R,3R,4R)-3,4-Bis-benzyloxy-5-methoxy-2-methyl-tetrahydro-furan-2-yl)-acetaldehyde 

Downstream Products

• 864712-71-0 Methanesulfonic acid (1S,2R,3R,4R)-2,3-bis-benzyloxy-10-(tert-butyl-diphenyl-silanyloxy)-4-methyl-1-((R)-2-oxo-[1,3]dioxolan-4-yl)-4-triethylsilanyloxy-decyl ester 
• 864712-72-1 {(2R,3R)-3-[(1S,2R,3R)-1,2-Bis-benzyloxy-9-(tert-butyl-diphenyl-silanyloxy)-3-methyl-3-triethylsilanyloxy-nonyl]-oxiranyl}-methanol 
• 887769-17-7 4,5-bis-benzyloxy-12-(tert-butyl-diphenyl-silanyloxy)-2,6-dimethyl-6-triethylsilanyloxy-1-trityloxy-dodecan-3-ol 
• 887769-18-8 C₇₀H₉₀O₆Si₂ 
• 887768-94-7 (E,4S,5R,6S,7R,8R)-6,7-bis(benzyloxy)-14-t-butyldiphenylsiloxy-8-triethylsiloxy-5-(4-methoxybenzyloxy)-2,4,8-trimethyltetradec-2-en-1-ol 
• 887769-02-0 (2S,3R,4R,5R,6R)-12-t-butyldiphenylsiloxy-3-methoxy-2,6-dimethyldodecane-1,4,5,6-tetrol 
• 864712-75-4 (E)-methyl 3-{(2R,3R)-3-[(2R,3R,4S,5R,6R)-4,5-bis(benzyloxy)-12-t-butyldiphenylsiloxy-6-triethylsiloxy-3-(4-methoxybenzyloxy)-6-methyldodecan-2-yl]-2-methyloxiran-2-yl}acrylate 
• 864712-77-6 (2S,3R,4S,5R,6R)-4,5-bis(benzyloxy)-12-t-butyldiphenylsiloxy-6-triethylsiloxy-3-(4-methoxybenzyloxy)-2,6-dimethyldodeca-1-ol 
• 887769-16-6 (2R,3R,4S,5R,6R)-4,5-Bis-benzyloxy-12-(tert-butyl-diphenyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2,6-dimethyl-6-triethylsilanyloxy-dodecanal 
• 864712-66-3 (2S,3R,4S,5R,6R)-4,5-bis(benzyloxy)-12-t-butyldiphenylsiloxy-6-triethylsiloxy-2,6-dimethyldodecane-1,3-diol 
• 887769-01-9 (R)-4-[(1S,2S,3R,4R)-2,3-bis(benzyloxy)-10-t-butyldiphenylsiloxy-4-triethylsiloxy-1-hydroxy-4-methyldecyl]-1,3-dioxolan-2-one 

Relevant articles and documents

Asymmetric synthesis of the polyol subunit of the macrolide antibiotic, ossamycin: A unique approach utilizing stereochemical specificity

An asymmetric synthesis of the C1-C16 polyol subunit 2 of the macrolide antibiotic ossamycin (1) has been achieved through stepwise carbon-chain elongation reaction from D-glucose, based on a chiral pool approach. An outstanding point of this strategy is

Asymmetric synthesis of the polyol subunit of the macrolide antibiotic, ossamycin

An asymmetric synthesis of the C1-C16 polyol subunit of the macrolide antibiotic, ossamycin, has been achieved through stepwise carbon-chain elongation reaction from D-glucose.