88822-01-9Relevant academic research and scientific papers
CIS-SELECTIVITY OF THE KINETIC DEPROTONATION OF DITHIOPROPANOATES.
Beslin, Pierre,Metzner, Patrick,Vallee, Yannick,Vialle, Jean
, p. 3617 - 3620 (1983)
Deprotonation of dithiopropanoates with LDA in THF solution at -78 degC afforded chiefly the cis lithium thioenolate in contrast with the trans enolization of most of carbonyl compounds.The cis geometry was proved by a thio-Claisen rearrangement.
