Tetrahedron Letters p. 3617 - 3620 (1983)
Update date:2022-08-04
Topics:
Beslin, Pierre
Metzner, Patrick
Vallee, Yannick
Vialle, Jean
Deprotonation of dithiopropanoates with LDA in THF solution at -78 degC afforded chiefly the cis lithium thioenolate in contrast with the trans enolization of most of carbonyl compounds.The cis geometry was proved by a thio-Claisen rearrangement.
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