88831-33-8Relevant academic research and scientific papers
Photochemistry of Aminoketones, XII. The Behaviour of N-Acylglycinate Rotamers in the Photochemical Glycine->Proline Conversion
Kernchen, Frank,Henning, Hans-Georg
, p. 253 - 268 (2007/10/02)
The rate of the diastereoselective generation of methyl 3r,2t-N-acyl-3-hydroxy-3-phenyl-prolinates 5 from n,?*-excited methyl N-acyl-N-(β-benzoylethyl)-glycinates 4 depends on the height of the barrier ΔGc(excit.) of amide rotation i
N-Benzoylethylation of Esters of Amino Acids
Haber, H.,Henning, H.-G.
, p. 509 - 511 (2007/10/02)
The synthesis of N-(β-benzoylethyl)-N-acyl-glycinates 2 for the photocyclization to proline-like compounds is accomplished in two steps.In the first step, a Mannich reaction, pure esters 1 of N-(β-benzoylethyl)aminoacids are preparated in an average yield
