888324-77-4Relevant academic research and scientific papers
Application of the intramolecular yamamoto vinylogous aldol reaction to the synthesis of macrolides
Abramite, Joseph A.,Sammakia, Tarek
, p. 2103 - 2106 (2008/02/02)
An intramolecular version of the Yamamoto vinylogous aldol reaction, a method that employs the bulky Lewis acid ATPH to control the site of aldolization, is described. This macrocyclization process is effective for the construction of 10-, 12-, and 14-mem
Stereoselective cascade reactions that incorporate a 7-exo acyl radical cyclization
Grant, Seth W.,Zhu, Koudi,Zhang, Yu,Castle, Steven L.
, p. 1867 - 1870 (2007/10/03)
Radical cascades that feature a 7-exo acyl radical cyclization followed by a 6-exo or 5-exo alkyl radical cyclization proceed with very good yields and diastereoselectivities. Two Stereocenters are created by the reaction, and a single isomeric product wa
