888721-97-9Relevant academic research and scientific papers
Highly regioselective transformation of out/out-equatorial bis(formylmethano)[60]fullerenes: Construction of dissymmetric [60]fullerene-centered triads
Ito, Hiroshi,Ishida, Yasuhiro,Saigo, Kazuhiko
, p. 4759 - 4765 (2007/10/03)
Three kinds of out/out-equatorial bis(formylmethano)[60]fullerenes (1b-d) were obtained by the tether-directed bifunctionalization of [60]fullerene with bis(α-formylsulfonium ylide)s. The condensation of aromatic amines with 1b-d proceeded with an unexpec
Regio- and diastereo-controlled synthesis of bis(formylmethano)[60]fullerenes and their application to the formation of [60]fullerene pearl-necklace polyimines
Ito, Hiroshi,Ishida, Yasuhiro,Saigo, Kazuhiko
, p. 3095 - 3098 (2007/10/03)
The tether-directed method was firstly applied to the biscyclopropanation of [60]fullerene via the addition-elimination reaction of bis(sulfonium ylide)s to give bis(formylmethano)[60]fullerenes with satisfactory regio- and stereoselectivity. The equatori
