88886-22-0

Basic information

• Product Name: platinum(IV)(chloride)3(1,2,3,4,9,9a-hexahydro-6,9a-di-p-tolylpyrimido[2,1-c][1,4]thiazine)(H₂O) chloride*H₂O
• CAS NO: 88886-22-0
• Molecular Weight: 709.424
• Mol File: 88886-22-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: platinum(IV)(chloride)3(1,2,3,4,9,9a-hexahydro-6,9a-di-p-tolylpyrimido[2,1-c][1,4]thiazine)(H₂O) chloride*H₂O(CAS DataBase Reference)
• NIST Chemistry Reference: platinum(IV)(chloride)3(1,2,3,4,9,9a-hexahydro-6,9a-di-p-tolylpyrimido[2,1-c][1,4]thiazine)(H₂O) chloride*H₂O(88886-22-0)
• EPA Substance Registry System: platinum(IV)(chloride)3(1,2,3,4,9,9a-hexahydro-6,9a-di-p-tolylpyrimido[2,1-c][1,4]thiazine)(H₂O) chloride*H₂O(88886-22-0)

Safety Data

• Hazardous Substances Data: 88886-22-0(Hazardous Substances Data)

Upstream product

• 71764-43-7 1,2,3,4,9,9a-hexahydro-6,9a-di(p-methylphenyl)pyrimido<2,1-c><1,4>thiazine 
• 13454-96-1 platinum(IV) chloride 

Relevant articles and documents

Ligating Properties of Model Bioheterocyclics: Part V - Complexes of Palladium(II) and Platinum(IV) Halides with 1,2,3,4,9,9a-Hexahydro-6,9a-diarylpyrimidothiazine Derivatives

Palladium(II) and platinum(IV) halides react with 1,2,3,4,9,9a-hexahydro-6,9a-diarylpyrimidothiazine derivatives (PTA) to form stable complexes of formulae *nH2O (where X = Cl, Br and n = 0, 0.5 or 1.0) and Cl*nH2O (n = 1 or 2) respectively.The spectral, conductance and magnetic data suggest square planar and octahedral stereochemistries around palladium(II) and platinum(IV) ions respectively.Thermal studies indicate the presence of one coordinated water molecule in platinum(IV) complexes and varying numbers of uncoordinated water molecules in platinum(IV) and palladium(II) complexes.Out of the three coordination sites (S, N, NH) in the ligand, only two (S and NH) are involved in coordination to palladium(II) and platinum(IV) ions.