88893-11-2Relevant academic research and scientific papers
Indium-mediated reactions of enamines in the presence of acid
Tussa, Laurent,Lebreton, Chrystele,Mosset, Paul
, p. 1064 - 1070 (1997)
The reaction of enamines with allyl bromide and metallic indium in THF to afford homoallylamines was greatly accelerated by the addition of one equivalent of a suitable carboxylic acid, such as acetic acid. It was established that the likely mechanism con
Triazolines. Part 32. Synthesis of 1-Alkyl-2-aminobenzimidazoles from 5-Amino-1-(2-nitroaryl)-1,2,3-triazolines
Erba, Emanuela,Mai, Giorgio,Pocar, Donato
, p. 2709 - 2712 (2007/10/02)
5-Amino-1-(2-nitroaryl)-1,2,3-triazolines 5 are converted into 1-alkyl-2-aminobenzimidazoles 7 in refluxing triethyl phosphite.The reaction occurs via thermal rearrangement of 5 followed by nitrogen elimination which produces N2-(2-nitroaryl)am
