889-65-6Relevant academic research and scientific papers
Branched-Chain Carbohydrate Lactones from a Samarium(II) Iodide-Promoted Serial Deoxygenation-Carbonyl Addition Reaction
Enholm, Eric J.,Jiang, Shujun,Abboud, Khalil
, p. 4061 - 4069 (2007/10/02)
A new deoxygenation-carbonyl addition reaction mediated by samarium(II) iodide (SmI2) in THF/HMPA was examined with carbohydrate lactones and several substrates containing an α-alkoxy carboxylic ester.In a single reaction, these compounds were deoxygenate
THE CONVERSION OF α- TO β-HYDROXY ESTERS BY A DEOXYGENATION/CONDENSATION REACTION PROMOTED BY SAMARIUM DIIODIDE
Enholm, Eric J.,Jiang, Shujun
, p. 313 - 316 (2007/10/02)
A mild reaction sequence begins by transforming an α-hydroxy ester to an α-benzoate ester.Next, the α-benzoate ester is both reductively deoxygenated with samarium diiodide and subsequently condensed with a ketone present in the reaction mixture to afford
