889109-06-2

Upstream product

• 858346-53-9 (2R,4aR,6R,7S,8aR,9aS,10aS)-6-(tert-Butyl-dimethyl-silanyloxy)-7-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-10a-methyl-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracene 
• 889109-05-1 (2S,3R,4aS,6R,7S,8aR)-3-(tert-Butyl-dimethyl-silanyloxy)-2-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-7-(4-methoxy-benzyloxy)-6-(4-methoxy-benzyloxymethyl)-4a-methyl-octahydro-pyrano[3,2-b]pyran 

Downstream Products

• 170707-15-0 C₄₇H₆₄O₉ 
• 889109-14-2 C₅₈H₈₂O₉SSi 
• 889109-16-4 2-{3-[7-benzyloxy-6-(2-benzyloxy-ethyl)-2,6,8a-trimethyl-2-vinyl-octahydro-pyrano[3,2-b]pyran-3-yloxy]-2-methyl-3-phenylsulfanyl-propyl}-4a,5-dimethyl-3,4,4a,7,8a,9,9a,10a-octahydro-2H-1,8,10-trioxa-anthracen-3-ol 
• 889109-19-7 9-[7-benzyloxy-6-(2-benzyloxy-ethyl)-2,6,8a-trimethyl-2-vinyl-octahydro-pyrano[3,2-b]pyran-3-yloxy]-4,5a,10-trimethyl-8-vinyl-4a,5a,6,6a,8,9,10,11,11a,12a,13,13a-dodecahydro-2H-1,5,7,12-tetraoxa-cyclohepta[b]anthracene 
• 889109-21-1 C₄₇H₆₂O₉ 
• 889109-08-4 (2S,3R,4aS,6R,7S,8aR)-3-(tert-Butyl-dimethyl-silanyloxy)-2-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-6-isopropenyl-7-(4-methoxy-benzyloxy)-4a-methyl-octahydro-pyrano[3,2-b]pyran 
• 889109-07-3 1-[(2R,3S,4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-6-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-3-(4-methoxy-benzyloxy)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-ethanol 
• 889109-13-1 tert-Butyl-[(2S,3R,4aS,8aS,9aR,10aR)-2-((R)-3-chloro-2-methyl-3-phenylsulfanyl-propyl)-4a,5-dimethyl-3,4,4a,7,8a,9,9a,10a-octahydro-2H-1,8,10-trioxa-anthracen-3-yloxy]-dimethyl-silane 
• 889109-12-0 tert-Butyl-[(2S,3R,4aS,8aS,9aR,10aR)-4a,5-dimethyl-2-((R)-2-methyl-3-phenylsulfanyl-propyl)-3,4,4a,7,8a,9,9a,10a-octahydro-2H-1,8,10-trioxa-anthracen-3-yloxy]-dimethyl-silane 

Relevant academic research and scientific papers

Improved synthesis of the A-G ring segment of brevetoxin B

An efficient synthesis of the A-G ring segment 2, a key intermediate for the total synthesis of brevetoxin B (1), was achieved in 37 steps and 5.0% overall yield. The intramolecular allylation of the O,S-acetal 22, prepared from the ABC ring segment 15 an