88948-23-6

Basic information

• Product Name: Alloisolongifolol-p-nitrobenzoate
• CAS NO: 88948-23-6
• Molecular Weight: 371.477
• Mol File: 88948-23-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Alloisolongifolol-p-nitrobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: Alloisolongifolol-p-nitrobenzoate(88948-23-6)
• EPA Substance Registry System: Alloisolongifolol-p-nitrobenzoate(88948-23-6)

Safety Data

• Hazardous Substances Data: 88948-23-6(Hazardous Substances Data)

Upstream product

• 87064-18-4 (-)-alloisolongifolene 
• 475-20-7 longifolene 
• 93053-18-0 Alloisolongifolol 
• 122-04-3 4-nitro-benzoyl chloride 

Relevant articles and documents

Alloisolongifolene: A Unique Acid-catalysed Isomer of Longifolene

A catalyst-specific rearrangement of longifolene (1) to a new tricyclic isomer, alloisolongifolene (10) is described.The structure (10) for alloisolongifolene has been derived by an X-ray crystal structure analysis of the p-nitrobenzoate (9) prepared from the primary alcohol (8) resulting from the hydroboration of the 10.Hydrolysis of the ester resulting from the Baeyer-Villiger oxidation of the methyl ketone (14) derived from the periodate-permanganate oxidation of 10 gives the trisnor C12-tertiary alcohol (16).Chromic acid oxidation of 10 generates the same carbon--cleaved ketone (14) and alloisolongifolic acid (15) derived from a terminal oxidation of the olefin.