88965-92-8

Upstream product

• 1009-14-9 phenyl butyl ketone 
• 1030268-21-3 trimethylsulfonium iodide 
• 109-72-8 n-butyllithium 
• 70-11-1 α-bromoacetophenone 
• 20826-80-6 2-phenylhex-1-ene 
• 180348-13-4 1-Bromo-2-phenylhexan-2-ol 

Downstream Products

• 88965-95-1 1-n-butyl-1-phenyl-2-(1,2,4-triazol-4-yl)ethanol 
• 79983-83-8 1-n-butyl-1-phenyl-2-(1,2,4-triazol-1-yl)ethanol 
• 73083-29-1 α-butylbenzeneacetaldehyde 
• 25755-73-1 2-benzene-2-butylethanol 
• 1338606-34-0 C₂₂H₂₉NO₄S 
• 1338606-22-6 C₂₁H₂₇NO₄S 

Relevant academic research and scientific papers

Syntheses of functionalized allylamines via lithiated intermediates

Lithiated allylamines are easily available by tin-lithium exchange from stannylated allylamines and are suitable nucleophiles for a wide range of conversions. With aldehydes and ketones, aminomethylated allyl alcohols are formed, whereas the reaction with α-brominated ketones gives rise to vinyl epoxides or aldehydes, depending on the reaction and workup conditions used. Copyright

New synthetic routes to 2-fluoro-2-phenylalkanoic acids

2-Fluoro-2-phenylalkanoic acids 2 are obtained by oxidation of the corresponding β-fluoro-β-phenyl alcohols 6. These compounds are shown to be accessible by two alternative pathways, either by bromo fluorination of α-alkyl styrenes 3, subsequent bromine-b

Rearrangement of (1,2,4-triazol-4-yl) ethanols to (1,2,4-triazol-1-yl)ethanols

The mechanism of rearrangement of β-hydroxyethyl-(1,2,4-triazoles) has been shown using crossover experiments to be intermolecular and free energy profiles show that reactions are thermodynamically-controlled.