889894-22-8

Basic information

• Product Name: Methanesulfonic acid, trifluoro-, 4-(2-propenyloxy)phenyl ester
• CAS NO: 889894-22-8
• Molecular Formula: C10H9F3O4S
• Molecular Weight: 282.24
• Mol File: 889894-22-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methanesulfonic acid, trifluoro-, 4-(2-propenyloxy)phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Methanesulfonic acid, trifluoro-, 4-(2-propenyloxy)phenyl ester(889894-22-8)
• EPA Substance Registry System: Methanesulfonic acid, trifluoro-, 4-(2-propenyloxy)phenyl ester(889894-22-8)

Safety Data

• Hazardous Substances Data: 889894-22-8(Hazardous Substances Data)

Upstream product

• 123-31-9 hydroquinone 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 6411-34-3 4-allyloxyphenol 

Downstream Products

• 901142-40-3 1,2-dibromo-3-(4-trifluoromethanesulfonyloxyphenyloxy)propane 

Relevant articles and documents

Efficient synthesis of propargylic ethers under the DBU conditions and its application to natural products synthesis

Conversion of dibromides carrying O-functional groups at adjacent positions to the corresponding propargylic ethers was successfully carried out under the DBU conditions through 2-bromo-1-alkenes as intermediates. The optically active γ-lactone-class natural products, such as (-)-muricatacin (4) and (R,R)-sapinofuranone B (5) were synthesized using the propargylic ether intermediate produced by the elimination reaction mentioned above.