Welcome to LookChem.com Sign In|Join Free

CAS

  • or

6411-34-3

Post Buying Request

6411-34-3 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

6411-34-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 6411-34-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,4,1 and 1 respectively; the second part has 2 digits, 3 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 6411-34:
(6*6)+(5*4)+(4*1)+(3*1)+(2*3)+(1*4)=73
73 % 10 = 3
So 6411-34-3 is a valid CAS Registry Number.
InChI:InChI=1/C9H10O2/c1-2-7-11-9-5-3-8(10)4-6-9/h2-6,10H,1,7H2

6411-34-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-prop-2-enoxyphenol

1.2 Other means of identification

Product number -
Other names 4-ALLYLOXY-PHENOL

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6411-34-3 SDS

6411-34-3Synthetic route

1,4-bis(allyloxy)benzene
37592-20-4

1,4-bis(allyloxy)benzene

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

Conditions
ConditionsYield
With ethylmagnesium chloride; iron(II) chloride In tetrahydrofuran; m-xylene at 20℃; for 1h;97%
allyl bromide
106-95-6

allyl bromide

hydroquinone
123-31-9

hydroquinone

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 12h; Heating;92%
With potassium carbonate In N,N-dimethyl-formamide at 60℃; for 22h;75%
With potassium carbonate In acetone for 24h; Reflux; Inert atmosphere;68%
1-allyloxy-4-prop-2-ynyloxy-benzene
153164-85-3

1-allyloxy-4-prop-2-ynyloxy-benzene

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

Conditions
ConditionsYield
With titanium(IV) isopropylate; chloro-trimethyl-silane; magnesium In tetrahydrofuran; ethyl acetate at 20℃; for 26h;91%
With palladium on activated charcoal; ethanolamine In water at 80℃; Inert atmosphere;74%
1-(allyloxy)-4-(2-phenylallyloxy)benzene

1-(allyloxy)-4-(2-phenylallyloxy)benzene

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

Conditions
ConditionsYield
With tert.-butyl lithium In tetrahydrofuran; pentane at -78℃; for 0.5h;86%
4-(Allyloxy)phenyl acetate

4-(Allyloxy)phenyl acetate

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

Conditions
ConditionsYield
With amberlyst-15 In methanol at 20℃; for 3h;85%
allyl (4-methoxyphenyl) ether
13391-35-0

allyl (4-methoxyphenyl) ether

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

Conditions
ConditionsYield
With boron dimethyl-trifluoro sulphide In dichloromethane at 0℃; for 0.0833333h;85%
p-benzoquinone
106-51-4

p-benzoquinone

A

2-allylhydroquinone

2-allylhydroquinone

B

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

C

hydroquinone
123-31-9

hydroquinone

Conditions
ConditionsYield
With allyltributylstanane In benzene for 3h; Ambient temperature; Irradiation;A 6%
B 26%
C 52%
allyl iodid
556-56-9

allyl iodid

hydroquinone
123-31-9

hydroquinone

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

Conditions
ConditionsYield
With potassium carbonate In acetone at 40℃; for 12h;41%
With potassium carbonate In acetone for 15h;
allyl bromide
106-95-6

allyl bromide

hydroquinone
123-31-9

hydroquinone

A

1,4-bis(allyloxy)benzene
37592-20-4

1,4-bis(allyloxy)benzene

B

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

Conditions
ConditionsYield
With potassium carbonate In acetone for 5h; Heating;A 40.0 g
B 27%
With tetra-(n-butyl)ammonium iodide; potassium carbonate In N,N-dimethyl-formamide at 20℃; for 6h;
allyl bromide
106-95-6

allyl bromide

hydroquinone
123-31-9

hydroquinone

A

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

B

hydroquinonediallyl ether

hydroquinonediallyl ether

Conditions
ConditionsYield
With potassium carbonate; acetone
4-(allyloxy)phenyl-4-methylbenzenesulfonate
157259-26-2

4-(allyloxy)phenyl-4-methylbenzenesulfonate

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

Conditions
ConditionsYield
With lithium trimethylmanganate; magnesium In tetrahydrofuran at 20℃; for 12h;
With potassium hydroxide In ethanol at 90℃;
4-((E)-3,7-Dimethyl-octa-2,6-dienyloxy)-phenol
58981-41-2

4-((E)-3,7-Dimethyl-octa-2,6-dienyloxy)-phenol

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 11 percent / KOH, O2 / methanol; H2O / 144 h / Heating
2: K2CO3 / acetone / Heating
View Scheme
4-((2E,5E)-3,6,10-Trimethyl-undeca-2,5,9-trienyloxy)-phenol
137362-24-4

4-((2E,5E)-3,6,10-Trimethyl-undeca-2,5,9-trienyloxy)-phenol

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 12 percent / KOH, O2 / methanol; H2O / 144 h / Heating
2: K2CO3 / acetone / Heating
View Scheme
hydroquinone
123-31-9

hydroquinone

allyl-X (X = Br or I)

allyl-X (X = Br or I)

A

1,4-bis(allyloxy)benzene
37592-20-4

1,4-bis(allyloxy)benzene

B

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

Conditions
ConditionsYield
With potassium carbonate In acetone
hydroquinone
123-31-9

hydroquinone

allyl - X

allyl - X

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

Conditions
ConditionsYield
With potassium carbonate In acetone
4-allyloxyphenol
6411-34-3

4-allyloxyphenol

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

4-(allyloxy)phenyl-4-methylbenzenesulfonate
157259-26-2

4-(allyloxy)phenyl-4-methylbenzenesulfonate

Conditions
ConditionsYield
With triethylamine In chloroform at 0℃; for 10h;99.2%
4-allyloxyphenol
6411-34-3

4-allyloxyphenol

methanesulfonyl chloride
124-63-0

methanesulfonyl chloride

4-(allyloxy)phenyl methanesulfonate

4-(allyloxy)phenyl methanesulfonate

Conditions
ConditionsYield
With triethylamine In ethyl acetate at 0 - 20℃; for 2h;99%
5-bromoacenaphthylene-1,2-dione
26254-35-3

5-bromoacenaphthylene-1,2-dione

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

5-(4-allyloxyphenoxy)acenaphthoquinone

5-(4-allyloxyphenoxy)acenaphthoquinone

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 60℃;93.7%
With potassium carbonate In N,N-dimethyl-formamide at 60℃;93.7%
4-allyloxyphenol
6411-34-3

4-allyloxyphenol

benzyl bromide
100-39-0

benzyl bromide

allyl (4-benzyloxyphenyl) ether
50666-95-0

allyl (4-benzyloxyphenyl) ether

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 85℃; for 4h;93%
4-allyloxyphenol
6411-34-3

4-allyloxyphenol

chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

1-allyloxy-4-(methoxymethoxy)benzene
476003-32-4

1-allyloxy-4-(methoxymethoxy)benzene

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran for 1h; Heating;92%
4-allyloxyphenol
6411-34-3

4-allyloxyphenol

3-(perfluorooctyl)propyl iodide
200112-75-0

3-(perfluorooctyl)propyl iodide

3-(4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoroundecoxy)phenoxy)prop-1-ene

3-(4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoroundecoxy)phenoxy)prop-1-ene

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 4h; Inert atmosphere; Reflux;91%
C24H34O11

C24H34O11

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

C42H50O13
929539-12-8

C42H50O13

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 0℃; for 6h;88%
trifluoromethylsulfonic anhydride
358-23-6

trifluoromethylsulfonic anhydride

4-allyloxyphenol
6411-34-3

4-allyloxyphenol

C10H9F3O4S
889894-22-8

C10H9F3O4S

Conditions
ConditionsYield
With pyridine In dichloromethane at 20℃; for 0.5h;88%
4-allyloxyphenol
6411-34-3

4-allyloxyphenol

O,O-diethyl benzylphosphonate
1080-32-6

O,O-diethyl benzylphosphonate

4-(allyloxy)phenyl ethyl benzylphosphonate

4-(allyloxy)phenyl ethyl benzylphosphonate

Conditions
ConditionsYield
Stage #1: O,O-diethyl benzylphosphonate With pyridine; trifluoromethylsulfonic anhydride In dichloromethane at 20℃; for 0.166667h; Sealed tube;
Stage #2: 4-allyloxyphenol In dichloromethane at 20℃; for 0.5h; Sealed tube;
88%

6411-34-3Relevant articles and documents

Protein Glycosylation through Sulfur Fluoride Exchange (SuFEx) Chemistry: The Key Role of a Fluorosulfate Thiolactoside

Marra, Alberto,Dong, Jiajia,Ma, Tiancheng,Giuntini, Stefano,Crescenzo, Elisa,Cerofolini, Linda,Martinucci, Marco,Luchinat, Claudio,Fragai, Marco,Nativi, Cristina,Dondoni, Alessandro

, p. 18981 - 18987 (2018)

Protein glycosylation is the most complex post-translational modification process. More than 50 % of human cells proteins are glycosylated, whereas bacteria such as E. coli do not have this modification machinery. Indeed, the carbohydrate residues in natural proteins affect their folding, immunogenicity, and stability toward proteases, besides controlling biological properties and activities. It is therefore important to introduce such structural modification in bioengineered proteins lacking the presence of carbohydrate residues. This is not trivial as it requires reagents and conditions compatible with the protein's stability and reactivity. This work reports on the introduction of lactose moieties in two natural proteins, namely ubiquitin (Ub) and l-asparaginase II (ANSII). The synthetic route employed is based on the sulfur(VI) fluoride exchange (SuFEx) coupling of a lactose tethered arylfluorosulfate (Lact-Ar-OSO2F) with the ?-NH2 group of lysine residues of the proteins. This metal-free click SuFEx reaction relies on the properties of the fluorosulfate employed, which is easily prepared in multigram scale from available precursors and reacts chemoselectively with the ?-NH2 group of lysine residues under mild conditions. Thus, iterative couplings of Lact-Ar-OSO2F to Ub and ANSII, afforded multiple glycosylations of these proteins so that up to three and four Lact-Ar-OSO2 groups were introduced in Ub and ANSII, respectively, via the formation of a sulfamoyl (OSO2-NH) linkage.

Nickel-catalyzed deallylation of aryl allyl ethers with hydrosilanes

Ding, Guangni,Fan, Sijie,Wang, Jingyang,Wang, Yu,Wu, Xiaoyu,Xie, Xiaomin,Yang, Liqun,Zhang, Zhaoguo

, (2021/09/28)

An efficient and mild catalytic deallylation method of aryl allyl ethers is developed, with commercially available Ni(COD)2 as catalyst precursor, simple substituted bipyridine as ligand and air-stable hydrosilanes. The process is compatible with a variety of functional groups and the desired phenol products can be obtained with excellent yields and selectivity. Besides, by detection or isolation of key intermediates, mechanism studies confirm that the deallylation undergoes η3-allylnickel intermediate pathway.

Enantioselective Synthesis of 3-Fluorochromanes via Iodine(I)/Iodine(III) Catalysis

Daniliuc, Constantin G.,Gilmour, Ryan,Neufeld, Jessica,Sarie, Jér?me C.,Thiehoff, Christian

supporting information, p. 15069 - 15075 (2020/06/17)

The chromane nucleus is common to a plenum of bioactive small molecules where it is frequently oxidized at position 3. Motivated by the importance of this position in conferring efficacy, and the prominence of bioisosterism in drug discovery, an iodine(I)/iodine(III) catalysis strategy to access enantioenriched 3-fluorochromanes is disclosed (up to 7:93 e.r.). In situ generation of ArIF2 enables the direct fluorocyclization of allyl phenyl ethers to generate novel scaffolds that manifest the stereoelectronic gauche effect. Mechanistic interrogation using deuterated probes confirms a stereospecific process consistent with a type IIinv pathway.

AMINATION AND HYDROXYLATION OF ARYLMETAL COMPOUNDS

-

Paragraph 0098; 0226; 0243, (2018/03/25)

In one aspect, the present disclosure provides methods of preparing a primary or secondary amine and hydroxylated aromatic compounds. In some embodiments, the aromatic compound may be unsubstituted, substituted, or contain one or more heteroatoms within the rings of the aromatic compound. The methods described herein may be carried out without the need for transition metal catalysts or harsh reaction conditions.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 6411-34-3