88994-68-7Relevant articles and documents
THE PREPARATION OF α-METHOXYALKYLIRON COMPLEXES: PRECURSORS OF SECONDARY CARBENEIRON COMPLEXES
Casey, Charles P.,Miles, William H.
, p. 333 - 338 (1983)
The addition of methyl-, n-butyl-, phenyl-, and p-tolyl-lithium reagents to (C5H5)(CO)2Fe=CHOCH3+ PF6- gives the respective α-methoxyalkyliron complexes in good yield.The addition of vinyllithium or vinylmagnesium bromide to (C5H5)(C
A method for the synthesis of carbene precursors from aldehydes and the metalates (η5-C5H5)(CO)2Fe- and (η5-C9H7)(CO)2Fe-
Theys, Ronald D.,Vargas, Roy M.,Wang, Qinwei,Hossain, M. Mahmun
, p. 1333 - 1339 (2008/10/08)
Nucleophilic addition of the metalate Cp(CO)2Fe-M+ (M = Na, K) to aldehydes RCHO (R = Ph, CH3, p-OCH3Ph, p-ClPh, p-CH3Ph, p-CF3Ph, o-OCH3Ph, and CH=C(CH3)2) and subsequent capture with ClSi(CH3)3 provided the (α-siloxyalkyl)iron complexes Cp(CO)2FeCH(OSiMe3)R in 42-79% yield. This new reaction was extended to the indenyl-ligated metalate In(CO)2Fe-Na+ with several aldehydes RCHO (R = Ph, CH3, p-OCH3Ph). Treatment of the (α-siloxyalkyl)iron complexes with trimethylsilyl triflate at between -25 and -78 °C, in the presence of alkenes, gave cyclopropanes through iron carbene complexes.
Synthesis and spectral characterization of a series of iron and ruthenium benzylidene complexes, Cp(CO)(L)M=CH(C6H4R)+ (M = Fe, Ru; L = CO, PPh3; R = p-H, p-F, p-CH3, p-OCH3). Barriers to a
Brookhart,Studabaker, William B.,Humphrey, M. Beth,Husk, G. Ronald
, p. 132 - 140 (2008/10/08)
The α-ether complexes Cp(CO)2Fe-CH(OCH3)C6H4R (7a, R = H; 7b, R = p-F; 7c, R = p-CH3; 7d, R = p-OCH3; 7e, R = m-OCH3; 7f, R = p-CF3), Cp(CO)2Ru-CH(OCH3